0000000000486028

AUTHOR

Janina Maultzsch

0000-0002-6088-2442

showing 2 related works from this author

Unveiling the oxidation behavior of liquid-phase exfoliated antimony nanosheets

2020

Abstract Antimonene, a monolayer of β-antimony, is increasingly attracting considerable attention, more than that of other monoelemental two-dimensional materials, due to its intriguing physical and chemical properties. Under ambient conditions, antimonene exhibits a high thermodynamic stability and good structural integrity. Some theoretical calculations predicted that antimonene would have a high oxidation tendency. However, it remains poorly investigated from the experimental point of view. In this work, we study the oxidation behavior of antimonene nanosheets (ANS) prepared by ultrasonication-assisted liquid-phase exfoliation. Using a set of forefront analytical techniques, a clear effe…

AntimonyMaterials scienceBand gapAnnealing (metallurgy)SonicationLiquid phasechemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencesAntimonyX-ray photoelectron spectroscopyChemical AnalysisNanosheetsMonolayerGeneral Materials ScienceUltraviolet Photoelectron SpectroscopyMaterialsMechanical EngineeringFísicaGeneral ChemistryQuímica021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesChemical engineeringchemistryMechanics of Materialsddc:540Chemical stability0210 nano-technologySurface Chemistry
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Two-Dimensional Antimony Oxide

2020

Two-dimensional (2D) antimony, so-called antimonene, can form antimonene oxide when exposed to air. We present different types of single- and few-layer antimony oxide structures, based on density functional theory (DFT) calculations. Depending on stoichiometry and bonding type, these novel 2D layers have different structural stability and electronic properties, ranging from topological insulators to semiconductors with direct and indirect band gaps between 2.0 and 4.9 eV. We discuss their vibrational properties and Raman spectra for experimental identification of the predicted structures.

Materials scienceOxideGeneral Physics and Astronomychemistry.chemical_elementFOS: Physical sciences01 natural scienceschemistry.chemical_compoundsymbols.namesakeAntimony0103 physical sciencesMesoscale and Nanoscale Physics (cond-mat.mes-hall)010306 general physicsMaterialsCondensed Matter - Materials ScienceCondensed Matter - Mesoscale and Nanoscale Physicsbusiness.industryFísicaMaterials Science (cond-mat.mtrl-sci)3. Good healthSemiconductorchemistryChemical physicsTopological insulatorsymbolsDirect and indirect band gapsDensity functional theoryAntimony oxidebusinessRaman spectroscopy
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