0000000000494467
AUTHOR
Shuichao Lin
showing 17 related works from this author
Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S-Adm)40]3+ (X=Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles
2017
Surface ligands play important roles in controlling the size and shape of metal nanoparticles and their surface properties. In this work, we demonstrate that the use of bulky thiolate ligands, along with halides, as the surface capping agent promotes the formation of plasmonic multiple-twinned Ag nanoparticles with high surface reactivities. The title nanocluster [Ag141X12(S-Adm)40]3+ (where X = Cl, Br, I; S-Adm = 1-adamantanethiolate) has a multiple-shell structure with an Ag71 core protected by a shell of Ag70X12(S-Adm)40. The Ag71 core can be considered as 20 frequency-two Ag10 tetrahedra fused together with a dislocation that resembles multiple-twinning in nanoparticles. The nanocluster…
From Symmetry Breaking to Unraveling the Origin of the Chirality of Ligated Au13Cu2 Nanoclusters
2018
A general method, using mixed ligands (here diphosphines and thiolates) is devised to turn an achiral metal cluster, Au13Cu2, into an enantiomeric pair by breaking (lowering) the overall molecular symmetry with the ligands. Using an achiral diphosphine, a racemic [Au13Cu2(DPPP)3(SPy)6]+ was prepared which crystallizes in centrosymmetric space groups. Using chiral diphosphines, enantioselective synthesis of an optically pure, enantiomeric pair of [Au13Cu2((2r,4r)/(2s,4s)‐BDPP)3(SPy)6]+ was achieved in one pot. Their circular dichroism (CD) spectra give perfect mirror images in the range of 250–500 nm with maximum anisotropy factors of 1.2×10−3. DFT calculations provided good correlations wit…
CCDC 1469852: Experimental Crystal Structure Determination
2016
Related Article: Yu Wang, Xian-Kai Wan, Liting Ren, Haifeng Su, Gang Li, Sami Malola, Shuichao Lin, Zichao Tang, Hannu Häkkinen, Boon K Teo, Quan-Ming Wang, and Nanfeng Zheng|2016|J.Am.Chem.Soc.|138|3278|doi:10.1021/jacs.5b12730
CCDC 1543483: Experimental Crystal Structure Determination
2017
Related Article: Liting Ren, Peng Yuan, Haifeng Su, Sami Malola, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen , Lansun Zheng, and Nanfeng Zheng|2017|J.Am.Chem.Soc.|139|13288|doi:10.1021/jacs.7b07926
CCDC 1814032: Experimental Crystal Structure Determination
2018
Related Article: Guocheng Deng, Sami Malola, Juanzhu Yan, Yingzi Han, Peng Yuan, Chaowei Zhao, Xiting Yuan, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2018|Angew.Chem.,Int.Ed.|57|3421|doi:10.1002/anie.201800327
CCDC 1428884: Experimental Crystal Structure Determination
2015
Related Article: Juanzhu Yan, Haifeng Su, Huayan Yang, Sami Malola, Shuichao Lin, Hannu Häkkinen, and Nanfeng Zheng|2015|J.Am.Chem.Soc.|137|11880|doi:10.1021/jacs.5b07186
CCDC 954905: Experimental Crystal Structure Determination
2013
Related Article: Huayan Yang , Yu Wang , Jing Lei , Lei Shi , Xiaohu Wu , Ville Mäkinen , Shuichao Lin , Zichao Tang , Jian He , Hannu Häkkinen , Lansun Zheng , and Nanfeng Zheng|2013|J.Am.Chem.Soc.|135|9568|doi:10.1021/ja402249s
CCDC 1814033: Experimental Crystal Structure Determination
2018
Related Article: Guocheng Deng, Sami Malola, Juanzhu Yan, Yingzi Han, Peng Yuan, Chaowei Zhao, Xiting Yuan, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2018|Angew.Chem.,Int.Ed.|57|3421|doi:10.1002/anie.201800327
CCDC 1508753: Experimental Crystal Structure Determination
2016
Related Article: Juanzhu Yan, Haifeng Su, Huayan Yang, Chengyi Hu, Sami Malola, Shuichao Lin, Boon K. Teo, Hannu Häkkinen, and Nanfeng Zheng|2016|J.Am.Chem.Soc.|138|12751|doi:10.1021/jacs.6b08100
CCDC 954903: Experimental Crystal Structure Determination
2013
Related Article: Huayan Yang , Yu Wang , Jing Lei , Lei Shi , Xiaohu Wu , Ville Mäkinen , Shuichao Lin , Zichao Tang , Jian He , Hannu Häkkinen , Lansun Zheng , and Nanfeng Zheng|2013|J.Am.Chem.Soc.|135|9568|doi:10.1021/ja402249s
CCDC 2022415: Experimental Crystal Structure Determination
2020
Related Article: Yu Wang, Haifeng Su, Liting Ren, Sami Malola, Shuichao Lin, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2016|Angew.Chem.,Int.Ed.|55|15152|doi:10.1002/anie.201609144
CCDC 1427733: Experimental Crystal Structure Determination
2015
Related Article: Yu Wang, Haifeng Su, Chaofa Xu, Gang Li, Lars Gell, Shuichao Lin, Zichao Tang, Hannu Häkkinen, and Nanfeng Zheng|2015|J.Am.Chem.Soc.|137|4324|doi:10.1021/jacs.5b01232
CCDC 954904: Experimental Crystal Structure Determination
2013
Related Article: Huayan Yang , Yu Wang , Jing Lei , Lei Shi , Xiaohu Wu , Ville Mäkinen , Shuichao Lin , Zichao Tang , Jian He , Hannu Häkkinen , Lansun Zheng , and Nanfeng Zheng|2013|J.Am.Chem.Soc.|135|9568|doi:10.1021/ja402249s
CCDC 1967410: Experimental Crystal Structure Determination
2020
Related Article: Hui Shen, Elli Selenius, Pengpeng Ruan, Xihua Li, Peng Yuan, Omar Lopez-Estrada, Sami Malola, Shuichao Lin, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2020|Chem.-Eur.J.|26|8465|doi:10.1002/chem.202001753
CCDC 1428883: Experimental Crystal Structure Determination
2015
Related Article: Juanzhu Yan, Haifeng Su, Huayan Yang, Sami Malola, Shuichao Lin, Hannu Häkkinen, and Nanfeng Zheng|2015|J.Am.Chem.Soc.|137|11880|doi:10.1021/jacs.5b07186
CCDC 1543485: Experimental Crystal Structure Determination
2017
Related Article: Liting Ren, Peng Yuan, Haifeng Su, Sami Malola, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen , Lansun Zheng, and Nanfeng Zheng|2017|J.Am.Chem.Soc.|139|13288|doi:10.1021/jacs.7b07926
CCDC 1814031: Experimental Crystal Structure Determination
2018
Related Article: Guocheng Deng, Sami Malola, Juanzhu Yan, Yingzi Han, Peng Yuan, Chaowei Zhao, Xiting Yuan, Shuichao Lin, Zichao Tang, Boon K. Teo, Hannu Häkkinen, Nanfeng Zheng|2018|Angew.Chem.,Int.Ed.|57|3421|doi:10.1002/anie.201800327