0000000000498247

AUTHOR

Constantinos J. Milios

0000-0002-1970-6295

showing 4 related works from this author

A [Cr2Ni] coordination polymer: slow relaxation of magnetization in quasi-one-dimensional ferromagnetic chains

2018

The reaction of [Cr3IIIO(OAc)6(H2O)3]NO3·AcOH with 2-hydroxynaphthaldehyde, 2-amino-isobutyric acid and NiCl2·6H2O in MeOH, under basic and solvothermal conditions, led to the formation of the quasi-1D coordination polymer {[CrIII2NiII(L)4(MeOH)2]}n (where L = the dianion of the Schiff base between 2-hydroxynaphthaldehyde and 2-amino-isobutyric acid), which behaves as a ferromagnetic chain, displaying slow relaxation of magnetization.

Materials scienceCoordination polymer010402 general chemistry01 natural sciencesCatalysisMETAL-ORGANIC FRAMEWORKSchemistry.chemical_compoundMagnetizationChain (algebraic topology)SYSTEMSNANO-MAGNETSABSORPTIONMaterials ChemistryFIELDANTIFERROMAGNETSANISOTROPYMOSSBAUER RELAXATIONSchiff base010405 organic chemistryNONLINEAR EXCITATIONSMetals and AlloysGeneral ChemistrySINGLE-MOLECULE MAGNETS0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographychemistryFerromagnetismCeramics and CompositesRelaxation (physics)Quasi one dimensional
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Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H2IBG) and divalent metal ions.

2012

We present a systematic study of the complexation of the new pseudopeptidic ligand isophthaloylbisglycine (H(2)IBG) with divalent metal ions of varying ionic radius. This work represents the initial employment of H(2)IBG in the coordination chemistry of alkaline earth, 3d transition, Zn(II) and Cd(II) metal elements. Infrared, NMR, thermal, magnetic, adsorption and theoretical studies of these compounds are also discussed.

chemistry.chemical_classificationAlkaline earth metalIonic radiusMagnetic Resonance SpectroscopySpectrophotometry InfraredInfraredLigandChemistryInorganic chemistryGlycineMolecular ConformationLigandsCoordination complexInorganic ChemistryMetalAdsorptionX-Ray DiffractionCoordination ComplexesMetalsDivalent metal ionsvisual_artvisual_art.visual_art_mediumQD0146ta116OligopeptidesDalton transactions (Cambridge, England : 2003)
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Hexanuclear Manganese(III) Single-Molecule Magnets

2003

ChemistryMagnetInorganic chemistrychemistry.chemical_elementMoleculeGeneral ChemistryManganeseGeneral MedicineCatalysisAngewandte Chemie
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CCDC 1833818: Experimental Crystal Structure Determination

2018

Related Article: Eirini Fotopoulou, Jose Martínez-Lillo, Milosz Siczek, Tadeusz Lis, Vassilis Tangoulis, Marco Evangelisti, Euan K. Brechin, Constantinos J. Milios|2018|Chem.Commun.|54|6153|doi:10.1039/C8CC02583E

Space GroupCrystallographyCrystal Systemcatena-[tetrakis(mu-2-methyl-2-(((2-oxidonaphthalen-1-yl)methylidene)amino)propanoato)-bis(methanol)-di-chromium(iii)-nickel(ii)]Crystal StructureCell ParametersExperimental 3D Coordinates
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