0000000000505240

AUTHOR

Yasuaki Einaga

showing 2 related works from this author

Influence of the Nature of Boron‐Doped Diamond Anodes on the Dehydrogenative Phenol‐Phenol Cross‐Coupling

2019

Boron doped diamondCoupling (electronics)chemistry.chemical_compoundMaterials sciencechemistryElectrochemistryPhenolElectrochemistryPhotochemistryCatalysisAnodeChemElectroChem
researchProduct

A solvent-directed stereoselective and electrocatalytic synthesis of diisoeugenol.

2018

A stereoselective and electrocatalytic coupling reaction of isoeugenol has been reported for the first time in a 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP)/boron-doped diamond (BDD) electrode system. This particular C-C bond formation and diastereoselectivity is driven by a solvate interaction between the radical species and another isoeugenol molecule. Due to an electrocatalytic cycle, only understoichiometric amounts of charge are necessary. Since electric current is directly employed as the oxidant, the reaction is metal and reagent-free. In addition, the electrolysis can be conducted in a very simple undivided beaker-type cell under constant current conditions. Therefore, the protocol is …

010402 general chemistry01 natural sciencesCatalysisCoupling reactionlaw.inventionMetalchemistry.chemical_compoundlawMaterials ChemistryMoleculeElectrolysis010405 organic chemistryMetals and AlloysGeneral ChemistryCombinatorial chemistry0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSolventIsoeugenolchemistryvisual_artElectrodeCeramics and Compositesvisual_art.visual_art_mediumStereoselectivityChemical communications (Cambridge, England)
researchProduct