0000000000513169

AUTHOR

Ruzal Sitdikov

showing 5 related works from this author

Phase-selective low molecular weight organogelators derived from allylated D-mannose

2022

In the last decades, synthesis and design of low molecular weight organogelators has gained increasing attention due to their versatile use in, for example, cosmetics, biomedicine and oil spill remediation. In this work, three potential gelators have been prepared from allylated d-mannose. Both the gelators and the corresponding gels formed were thoroughly characterized by crystallography, FTIR spectroscopy, SEM, rheometry and NMR spectroscopy, in solution and in solid state. The results showed that two of the compounds phase-selectively form gels with hydrocarbon solvents. The most promising gelator compound is alkene terminated, with the unsaturated end functionality not critical for gel …

monosakkariditgeelitD-mannoosiLMWOGphase selectivityOrganic ChemistryinfrapunaspektroskopiaGeneral MedicineAlkenesgelskidetiedeBiochemistryAnalytical ChemistryMolecular WeightPetroleum PollutionhyötykäyttöNMR-spektroskopiahiilihydraatitGelsMannoseD-mannosesolid state NMR spectroscop
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Improved synthesis and application of conjugation-amenable polyols from d-mannose

2020

A series of polyhydroxyl sulfides and triazoles was prepared by reacting allyl and propargyl D-mannose derivatives with selected thiols and azides in thiol–ene and Huisgen click reactions. Conformational analysis by NMR spectroscopy proved that the intrinsic rigidity and linear conformation of the mannose derived polyol backbone is retained in the final click products in solution. Single crystal X-ray structure determination of one of the compounds prepared further verified that the linear conformation of the polyol segment is also retained in the solid state. In addition, an improved method for direct Barbier-type propargylation of unprotected D-mannose is reported. The new reaction protoc…

sokerialkoholitkemiallinen synteesisynthesis
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CCDC 2149492: Experimental Crystal Structure Determination

2022

Related Article: Ida Mattsson, Manu Lahtinen, Ruzal Sitdikov, Bianca Wank, Tiina Saloranta-Simell, Reko Leino|2022|Carbohydr.Res.|518|108596|doi:10.1016/j.carres.2022.108596

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters1-(14-dioxaspiro[4.5]decan-2-yl)-2-(3-propyl-14-dioxaspiro[4.5]decan-2-yl)ethane-12-diolExperimental 3D Coordinates
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CCDC 2149491: Experimental Crystal Structure Determination

2022

Related Article: Ida Mattsson, Manu Lahtinen, Ruzal Sitdikov, Bianca Wank, Tiina Saloranta-Simell, Reko Leino|2022|Carbohydr.Res.|518|108596|doi:10.1016/j.carres.2022.108596

Space GroupCrystallography1-(14-dioxaspiro[4.5]decan-2-yl)-2-[3-(prop-2-en-1-yl)-14-dioxaspiro[4.5]decan-2-yl]ethane-12-diolCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1956436: Experimental Crystal Structure Determination

2020

Related Article: Ida Mattsson, Ruzal Sitdikov, Andreas C. M. Gunell, Manu Lahtinen, Tiina Saloranta-Simell, Reko Leino|2020|RSC Advances|10|3960|doi:10.1039/C9RA10378C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2R3R4R5R6S)-7-(1-benzyl-1H-123-triazol-4-yl)heptane-123456-hexaolExperimental 3D Coordinates
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