Photocycle of point defects in highly- and weakly-germanium doped silica revealed by transient absorption measurements with femtosecond tunable pump.

2022

AbstractWe report pump-probe transient absorption measurements addressing the photocycle of the Germanium lone pair center (GLPC) point defect with an unprecedented time resolution. The GLPC is a model point defect with a simple and well-understood electronic structure, highly relevant for several applications. Therefore, a full explanation of its photocycle is fundamental to understand the relaxation mechanisms of such molecular-like systems in solid state. The experiment, carried out exciting the sample resonantly with the ultraviolet (UV) GLPC absorption band peaked at 5.1 eV, gave us the possibility to follow the defect excitation-relaxation dynamics from the femto-picosecond to the nan…

Resonance Raman of oxygen dangling bonds in amorphous silicon dioxide

2017

We investigate the origin of a resonance Raman band induced by ionizing radiation in amorphous silicon dioxide (silica glass), which can be detected under ultraviolet laser excitation. A silica sample, rich of oxygen-excess related defects, was prepared by treating some length of a pure-silica-core multimode fiber in an O2 atmosphere (at high temperature and pressure) and by irradiating it with X-rays at 10 MGy(SiO2) dose. A micro-Raman study revealed a gaussian band peaking at 896 cm−1 with a full width at half maximum of 32 cm−1, which could be detected by exciting the sample with the 325-nm line of a HeCd laser. This spectral feature is absent in the Raman spectra performed with the 442-…

Radiation responses of Yb/Er-doped phosphosilicate optical fibers: hardening mechanisms related to Ce-codoping

2012

International audience; In this paper, we investigated the origins of the Ce positive influence on the radiation response of Yb/Er-doped phosphosilicate optical fibers. To this purpose, we carried out during γ-irradiations an online characterization on active optical fiber prototypes, made with different Ce concentrations and integrated in optical amplifiers. The hardening effect of Ce-codoping is highlighted, as well as some aspects related to the radiation response of the phosphosilicate host glass of the active optical fibers.

Irradiation induced defects in fluorine doped silica

2007

International audience

X-ray irradiation effects on a specific multistep Ge-doped fiber

2010

International audience; The study of point defects generation in optical fibers plays an important role with regards to their use and application in different domains. Their design and elaboration processes (dopants type, concentration, refractive index profile, drawing conditions...) govern their responses and more generally their radiation hardness [1]. In this work we investigated, the influence of 10 keV X-ray irradiations on a set of specific germanosilicate optical fibers elaborated from the same preform at different drawing conditions. The germanium doping levels along the fiber core diameter was specifically designed to follow a two-step distribution in order to highlight the Ge-con…

Influence of fluorine on the fiber performance studied through the NBOHC-related 1.9 eV microluminescence

2012

International audience; The distribution of Non Bridging Oxygen Hole Centers (NBOHC) in Fluorine doped optical fibers was investigated by confocal microluminescence spectroscopy monitoring the characteristic 1.9 eV luminescence band. The results show that these defects are generated by the fiber drawing and their concentration further increases after γ irradiation. The NBOHC profile along the fiber is anticorrelated to the fluorine content. This finding agrees with the role of fluorine in the fiber toughness and is discussed from the microscopic point of view on the basis of previous works.

Paramagnetic germanium-related centers induced by energetic radiation in silica based devices

2009

Durcissement aux radiations de fibres optiques dopées terres rares et d'amplificateurs 'a fibres optiques

2011

National audience; Cette étude vise à comprendre les effets d'une irradiation Ȗ sur les propriétés optiques et structurales des fibres dopées aux Terres Rares en vue de leur utilisation dans des amplificateurs à fibre réalisés pour des applications spatiales. L'enjeu majeur de durcissement de ces composants est abordé via des techniques telles que le chargement en hydrogène et/ou le co-dopage au Cérium du cœur des fibres optiques. L'identification des centres responsables de l'atténuation induite par irradiation et la compréhension des mécanismes de dégradation mis en jeu sont des étapes indispensables au développement de ces fibres.

Radiation Effects on Silica-Based Preforms and Optical Fibers - II: Coupling Ab Initio Simulations and Experiments

2008

International audience; Both experimental and theoretical approaches are combined to study the nature of precursor sites and radiation-induced point defects in pure and germanium-doped amorphous silica-based glasses.

Thermal bleaching of gamma-induced-defects in optical fibers

2012

International audience; Ge-doped and F-doped gamma-irradiated fibers with a maximum accumulated dose of 10 MGy were subjected to isochronal annealing treatments up to 750°C. The thermal treatment influence on the point defect generation and transformation were investigated through Radiation Induced Attenuation (RIA) changes in the visible and IR spectral domains. The thermal bleaching of gammainduced-defects depends on both temperature and composition of optical fibers.