0000000000528334
AUTHOR
Hassan M. Helmy
Sr and O isotope analyses reveal Late Cretaceous shark teeth in Iron Age strata of Jerusalem
Experimental determination of the phase relations of Pt and Pd antimonides and bismuthinides in the Fe-Ni-Cu sulfide systems between 1100 and 700 °C
Abstract The stability relations of Pt and Pd antimonides and bismuthinides in the Sb- and Bi-bearing Fe-Ni-Cu sulfide systems have been experimentally determined at temperatures between 1100 and 700 °C in evacuated silica tubes. Both PtSb and PdSb are stable as immiscible liquids at temperatures above 1100 and 1000 °C, respectively. The Fe-Ni-Cu-sulfide melt that coexists with the immiscible antimonide melt can dissolve up to 3.8 wt% Sb at 1100 °C, whereas monosulfide solid solution (mss) dissolves very low amounts of Sb over the entire 1100–700 °C temperature range. The liquidus of Pt-antimonides and Pdantimonides are above 980 and 750 °C, respectively. Bismuth does not form immiscible me…