0000000000537712
AUTHOR
Maitham H. Majeed
Synthesis and characterization of chiral phosphirane derivatives of [(μ-H)4Ru4(CO)12] and their application in the hydrogenation of an α,β-unsaturated carboxylic acid
Abstract Ruthenium clusters containing the chiral binaphthyl-derived mono-phosphiranes [(S)-([1,1′-binaphthalen]-2-yl)phosphirane] (S)-1a, [(R)-(2′-methoxy-1,1′-binaphthyl-2-yl)phosphirane] (R)-1b, and the diphosphirane [2,2′-di(phosphiran-1-yl)-1,1′-binaphthalene] (S)-1c have been synthesized and characterized. The clusters are [(μ-H)4Ru4(CO)11((S)-1a)] (S)-2, [(μ-H)4Ru4(CO)11((R)-1b)] (R)-3, 1,1-[(μ-H)4Ru4(CO)10((S)-1c)] (S)-4, [(μ-H)4Ru4(CO)11((S)-binaphthyl-P(s)(H)Et)] (S,Sp)-5, [(μ-H)4Ru4(CO)11((S)-binaphthyl-P(R)(H)Et)] (S,Rp)-6, [(μ-H)4Ru4(CO)11((R)-binaphthyl-P(s)(H)Et)] (R,Sp)-7, [(μ-H)4Ru4(CO)11((R)-binaphthyl-P(R)(H)Et)] (R,Rp)-8 and the phosphinidene-capped triruthenium cluster …
CCDC 1531251: Experimental Crystal Structure Determination
Related Article: Ahmed F. Abdel-Magied, Maitham H. Majeed, Manuel F. Abelairas-Edesa, Arne Ficks, Radwa M. Ashour, Ahibur Rahaman, William Clegg, Matti Haukka, Lee J. Higham, Ebbe Nordlander|2017|J.Organomet.Chem.|849-850|71|doi:10.1016/j.jorganchem.2017.05.031
CCDC 1531250: Experimental Crystal Structure Determination
Related Article: Ahmed F. Abdel-Magied, Maitham H. Majeed, Manuel F. Abelairas-Edesa, Arne Ficks, Radwa M. Ashour, Ahibur Rahaman, William Clegg, Matti Haukka, Lee J. Higham, Ebbe Nordlander|2017|J.Organomet.Chem.|849-850|71|doi:10.1016/j.jorganchem.2017.05.031
CCDC 1531252: Experimental Crystal Structure Determination
Related Article: Ahmed F. Abdel-Magied, Maitham H. Majeed, Manuel F. Abelairas-Edesa, Arne Ficks, Radwa M. Ashour, Ahibur Rahaman, William Clegg, Matti Haukka, Lee J. Higham, Ebbe Nordlander|2017|J.Organomet.Chem.|849-850|71|doi:10.1016/j.jorganchem.2017.05.031