showing 13 related works from this author
Switching of easy-axis to easy-plane anisotropy in cobalt(ii) complexes
2021
A tetranuclear cubane-type complex [Co4(ntfa)4(CH3O)4(CH3OH)4] (1) with a {Co4O4} core, and a mononuclear complex [Co(ntfa)2(CH3OH)2] (2) have been rationally obtained by adjusting the ratio of the β-diketonate and Co(II) ions, with the synthetic processes being monitored by in situ microcalorimetry. Then, following synthetic conditions to obtain 2, but using three distinct N-donor coligands - 2,2'-bipyridyl (bpy), 6,6'-dimethyl-2,2'-bipyridyl (6,6-(CH3)2-bpy) and 5,5'-dimethyl-2,2'-bipyridyl (5,5-(CH3)2-bpy) - three novel mononuclear complexes have been obtained, [Co(ntfa)2(bpy)2] (3), [Co(ntfa)2(6,6-(CH3)2- bpy)2] (4) and [Co(ntfa)2(5,5-(CH3)2-bpy)2] (5). The introduction of different cap…
Modulation of the magnetic anisotropy of octahedral cobalt(ii) single-ion magnets by fine-tuning the axial coordination microenvironment
2019
Two mononuclear cobalt(II) complexes, with the formulas [Co(2,6-dfba)2(bpp)2(H2O)2]n (1) and [Co(2,6-dfba)2(bpe)2(H2O)2]n (2) (2,6-Hdfba = 2,6-difluorobenzoic acid, bpp = 1,3-bis(4-pyridyl)propane, bpe = 1,2-bis(4-pyridyl)ethylene), have been synthesized by combining Co(II) ions with benzoate derivatives and two homogeneous N-donor ligands, respectively. Constrained by the analogous CoN2O4 coordination spheres, the discretely hexa-coordinated Co(II) cores in both complexes display stretched octahedral geometries. The equatorial environments in both complexes are identical, whereas the axial sites are finely modulated by the different chemical natures of the terminal N-donor ligands. The com…
Solvent-induced single-crystal-to-single-crystal transformation and tunable magnetic properties of 1D azido-Cu(ii) chains with a carboxylate bridge
2019
By means of the solvent effect, three new azido-copper 1D coordination polymers, [Cu(4-aba)(N3)] (1), [Cu(4-aba)(N3)(CH3OH)] (2), and [Cu(4-aba)(N3)(C2H5OH)] (3) (4-aba = 4-azidobenzoic acid), were successfully prepared in the presence of Cu2+ ion, NaN3 and 4-azidobenzoic acid. Interestingly, 1 can be employed as a precursor and transformed to 2 and 3via the coordination of methanol or ethanol, respectively. Meanwhile, the identical products of 1, namely 1a and 1b, could be obtained from both 2 and 3 by a dealcoholized process. As a result, the geometric configurations of Cu(II) ions vary from the tetracoordinated square-planar in 1 to the hexacoordinated octahedron in 2 or 3. Compound 1 di…
CCDC 1860913: Experimental Crystal Structure Determination
2019
Related Article: Xiangyu Liu, Xiufang Ma, Jinhui Yang, Shuchang Luo, Zheng Wang, Jesús Ferrando-Soria, Yulong Ma, Quan Shi, Emilio Pardo|2019|Dalton Trans.|48|11268|doi:10.1039/C9DT02031D
CCDC 1878502: Experimental Crystal Structure Determination
2019
Related Article: Yuewei Wu, Danian Tian, Jesús Ferrando-Soria, Joan Cano, Lei Yin, Zhongwen Ouyang, Zhenxing Wang, Shuchang Luo, Xiangyu Liu, Emilio Pardo|2019|Inorg.Chem.Front.|6|848|doi:10.1039/C8QI01373J
CCDC 1860912: Experimental Crystal Structure Determination
2019
Related Article: Xiangyu Liu, Xiufang Ma, Jinhui Yang, Shuchang Luo, Zheng Wang, Jesús Ferrando-Soria, Yulong Ma, Quan Shi, Emilio Pardo|2019|Dalton Trans.|48|11268|doi:10.1039/C9DT02031D
CCDC 2100779: Experimental Crystal Structure Determination
2021
Related Article: Yuewei Wu, Jing Xi, Tongtong Xiao, Jes��s Ferrando-Soria, Zhong-Wen Ouyang, Zhenxing Wang, Shuchang Luo, Xiangyu Liu, Emilio Pardo|2020|Inorg.Chem.Front.|8|5158|doi:10.1039/D1QI01208H
CCDC 2100777: Experimental Crystal Structure Determination
2021
Related Article: Yuewei Wu, Jing Xi, Tongtong Xiao, Jes��s Ferrando-Soria, Zhong-Wen Ouyang, Zhenxing Wang, Shuchang Luo, Xiangyu Liu, Emilio Pardo|2020|Inorg.Chem.Front.|8|5158|doi:10.1039/D1QI01208H
CCDC 2100778: Experimental Crystal Structure Determination
2021
Related Article: Yuewei Wu, Jing Xi, Tongtong Xiao, Jes��s Ferrando-Soria, Zhong-Wen Ouyang, Zhenxing Wang, Shuchang Luo, Xiangyu Liu, Emilio Pardo|2020|Inorg.Chem.Front.|8|5158|doi:10.1039/D1QI01208H
CCDC 1860914: Experimental Crystal Structure Determination
2019
Related Article: Xiangyu Liu, Xiufang Ma, Jinhui Yang, Shuchang Luo, Zheng Wang, Jesús Ferrando-Soria, Yulong Ma, Quan Shi, Emilio Pardo|2019|Dalton Trans.|48|11268|doi:10.1039/C9DT02031D
CCDC 1878500: Experimental Crystal Structure Determination
2019
Related Article: Yuewei Wu, Danian Tian, Jesús Ferrando-Soria, Joan Cano, Lei Yin, Zhongwen Ouyang, Zhenxing Wang, Shuchang Luo, Xiangyu Liu, Emilio Pardo|2019|Inorg.Chem.Front.|6|848|doi:10.1039/C8QI01373J
CCDC 2100781: Experimental Crystal Structure Determination
2021
Related Article: Yuewei Wu, Jing Xi, Tongtong Xiao, Jes��s Ferrando-Soria, Zhong-Wen Ouyang, Zhenxing Wang, Shuchang Luo, Xiangyu Liu, Emilio Pardo|2020|Inorg.Chem.Front.|8|5158|doi:10.1039/D1QI01208H
CCDC 2100780: Experimental Crystal Structure Determination
2021
Related Article: Yuewei Wu, Jing Xi, Tongtong Xiao, Jes��s Ferrando-Soria, Zhong-Wen Ouyang, Zhenxing Wang, Shuchang Luo, Xiangyu Liu, Emilio Pardo|2020|Inorg.Chem.Front.|8|5158|doi:10.1039/D1QI01208H