0000000000547774
AUTHOR
Bernhard Beile
Stereoselective Synthesis of Polycyclic Thiopyrans
The reaction of benzothiete (1) and the bicyclic alkenes 5, 7, 9, or 12 shows a very high π side selectivity (de > 95%) in the formation of the polycyclic thiopyrans 6, 8, 10, 11, 13, and 14.
ChemInform Abstract: Stereoselective Synthesis of Polycyclic Thiopyrans.
Reactions of benzothiete (I) with bicyclic alkenes exhibit very high π-side selectivity in the formation of polycyclic thiopyrans.