0000000000587049
AUTHOR
Klaus Wurst
Coexistence of ferro- and antiferromagnetic interactions in a metal-organic radical-based (6,3)-helical network with large channels.
A metal–organic open-framework with an unprecedented (6,3)-helical topology, large channels and mixed ferro- and antiferromagnetic interactions has been synthesized using a three-connecting tricarboxylic polychlorotriphenylmethyl radical and Co(II) ions. Lloret Pastor, Francisco, Francisco.Lloret@uv.es
A New Valence Tautomerism Example in an Electroactive Ferrocene Substituted Triphenylmethyl Radical
A new molecular system combining an open-shell organic radical that acts as an acceptor group, different from an o-quinone moiety, covalently linked to a ferrocene moiety, acting as the donor group, is shown to exhibit valence tautomerism.