0000000000594072
AUTHOR
Richa Vinayak
Solvent Modulated Assembly of Two Ni(II) Complexes: Syntheses, Structures and Magnetic Properties
A dinuclear [Ni2(L)2(DMSO)2(MeOH)2] (1) and a tetra-nuclear [Ni4(L)4(DMF)2(H2O)2].DMF (2) Ni(II) complexes have been prepared by treating nickel nitrate hexahydrate with the Schiff base ligand H2L (H2L=(E)-2-(2-hydroxybenzyliden)amino-4-nitrophenol) in a one-pot reaction. Complex 1 was obtained after recrystallization of the precipitate from the reaction with a 1:1:1 mixture of DMSO/CH2Cl2/MeOH. In contrast, the tetrameric complex 2 was obtained after slow evaporation of the filtrate. Both complexes were characterized by analytical, thermogravimetric, optical and magnetic techniques. The solid state molecular structures of 1 and 2 were determined by single crystal X-ray crystallography. Com…
CCDC 1499648: Experimental Crystal Structure Determination
Related Article: Richa Vinayak, A. Harinath, Carlos J. Gomez-Garcıa, Tarun K. Panda, Samia Benmansour, and Hari Pada Nayek|2016|Chem. Sel.|1|6532|doi:10.1002/slct.201601385
CCDC 1499647: Experimental Crystal Structure Determination
Related Article: Richa Vinayak, A. Harinath, Carlos J. Gomez-Garcıa, Tarun K. Panda, Samia Benmansour, and Hari Pada Nayek|2016|Chem. Sel.|1|6532|doi:10.1002/slct.201601385