0000000000594165
AUTHOR
Sanjib Giri
Double azido-bridged and mixed-bridged binuclear copper(II) and nickel(II) compounds with N,N,O-donor Schiff bases: Synthesis, structure, magnetic and DFT study
Abstract Two dinuclear complexes μ1,1-azido bridged [Cu(L1)(N3)]2 (1) and μ-phenoxo, μ1,1-azido bridged [Ni2(L2)2(μ1,1-N3)(N3) H2O] (2) bearing HL1 and HL2 as a blocking co-ligands produced by the 1:1 condensation of N-benzyl ethylenediamine with ortho-hydroxy acetophenone and N-methyl propanediamine with 3-methoxy salicylaldehyde respectively, have been synthesized and successfully characterized by elemental analyses, IR and electronic spectroscopy, single-crystal X-ray diffraction, variable temperature magnetic study and DFT studies. X-ray crystal structures of 1 reveal that the Cu(II) ion displays a five-coordinate square pyramidal coordination with a centro-symmetric μ1,1-azido bridging…
CCDC 998456: Experimental Crystal Structure Determination
Related Article: Partha Pratim Chakrabarty, Sanjib Giri, Dieter Schollmeyer, Hiroshi Sakiyama, Masahiro Mikuriya, Ananda Sarkar, Sandip Saha|2015|Polyhedron|89|49|doi:10.1016/j.poly.2014.12.033
CCDC 998455: Experimental Crystal Structure Determination
Related Article: Partha Pratim Chakrabarty, Sanjib Giri, Dieter Schollmeyer, Hiroshi Sakiyama, Masahiro Mikuriya, Ananda Sarkar, Sandip Saha|2015|Polyhedron|89|49|doi:10.1016/j.poly.2014.12.033