0000000000594702

AUTHOR

Saritha Nellutla

showing 2 related works from this author

Highly Anisotropic Rhenium(IV) Complexes: New Examples of Mononuclear Single-Molecule Magnets

2013

The rhenium(IV) complex (NBu4)2[ReBr4(ox)] (1) (ox = oxalate and NBu4(+) = tetra-n-butylammonium cation) has been prepared and its crystal structure determined by X-ray diffraction. The structure is made up of discrete [ReBr4(ox)](2-) anions and bulky NBu4(+) cations. Each [ReBr4(ox)](2-) anion is surrounded by six NBu4(+) cations, which preclude any significant intermolecular contact between the anionic entities, the shortest rhenium···rhenium distance being 9.373(1) Å. Variable temperature dc and ac magnetic susceptibility measurements and field-dependent magnetization experiments on polycrystalline samples of 1 reveal the occurrence of highly anisotropic magnetically isolated Re(IV) cent…

010405 organic chemistryRelaxation (NMR)Inorganic chemistrychemistry.chemical_elementGeneral ChemistryCrystal structureRhenium010402 general chemistry01 natural sciencesBiochemistryMagnetic susceptibilityCatalysisOxalate3. Good health0104 chemical sciencesMagnetizationchemistry.chemical_compoundCrystallographyColloid and Surface ChemistrychemistryMolecule[PHYS.COND.CM-SCE]Physics [physics]/Condensed Matter [cond-mat]/Strongly Correlated Electrons [cond-mat.str-el]IsostructuralComputingMilieux_MISCELLANEOUSJournal of the American Chemical Society
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CCDC 854108: Experimental Crystal Structure Determination

2014

Related Article: José Martínez-Lillo , Teresa F. Mastropietro , Elsa Lhotel , Carley Paulsen , Joan Cano , Giovanni De Munno , Juan Faus , Francesc Lloret , Miguel Julve , Saritha Nellutla , and J. Krzystek|2013|J.Am.Chem.Soc.|135|13737|doi:10.1021/ja403154z

Space GroupCrystallographybis(Tetra-n-butylammonium) tetrabromo-(oxalato)-rhenium(iv)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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