0000000000595761
AUTHOR
Shengdong Wang
Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel complexes: Their synthesis, characterization and catalytic behavior toward ethylene
Propyl substituted 4-arylimino-1,2,3-trihydroacridylnickel dihalide complexes were designed and prepared by metal-induced template reaction with NiCl2 center dot 6H(2)O or (DME)NiBr2. They were characterized by infrared spectroscopy and elemental analysis. Single crystal X-ray crystallography of representative complex Ni3 revealed a distorted trigonal bipyramidal geometry around nickel. The catalytic activities of the title nickel complexes were negatively affected by propyl substituent on their backbone when comparing with the results by unsubstituted ones. With the activation of diethylaluminium chloride, all nickel complexes exhibited moderate activity (up to 5.10 x 10(5) g mol(-1)(Ni) h…
CCDC 1043484: Experimental Crystal Structure Determination
Related Article: Shengdong Wang, Wenjuan Zhang, Shizhen Du, Sin Asuha, Zygmunt Flisak, Wen-Hua Sun|2015|J.Organomet.Chem.|798|408|doi:10.1016/j.jorganchem.2015.05.001