0000000000599944

AUTHOR

A.a.g. Santiago

showing 2 related works from this author

Spray pyrolysis synthesis and characterization of Mg1-xSrxMoO4 heterostructure with white light emission

2020

[EN] Molybdates are inorganic materials with great potential in white phosphors application, being an alternative to traditional lighting sources. In this study, we report the synthesis and characterization of Mg1-xSrxMoO4 (x = 0, 0.25, 0.50, 0.75, and 1) powders with white light-emitting properties. Using X-ray diffraction, the formation of the monoclinic beta-MgMoO4 phase was observed for x = 0 and the formation of the tetragonal scheelite phase of SrMoO4 was observed for x = 1. The formation of a heterostructure composed of both phases was found for compositions with x = 0.25, 0.50 and 0.75. Scanning and trasmission electron microscopy images showed that the Mg1-xSrxMoO4 particles exhibi…

White emissionPhotoluminescenceMaterials scienceAnalytical chemistryNanoparticlePhosphor02 engineering and technology010402 general chemistry01 natural sciencesTetragonal crystal systemsymbols.namesakePhase (matter)Materials ChemistryEmission spectrumPhotoluminescenceUltrasonic spray pyrolysisMolybdateMechanical EngineeringMetals and Alloys021001 nanoscience & nanotechnology0104 chemical sciencesMechanics of MaterialsFISICA APLICADARaman spectroscopysymbols0210 nano-technologyRaman spectroscopyMonoclinic crystal systemJournal of Alloys and Compounds
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Integrated experimental and theoretical study on the phase transition and photoluminescent properties of ZrO2:xTb3+ (x=1, 2, 4 and 8 mol %)

2021

Abstract Zirconia (ZrO2) has been intensively studied as an important ceramic material, and numerous technological applications have been found. The present work deals with synthesizing and characterizing the phase transition (cubic vs tetragonal) and photoluminescence emissions of ZrO2:xTb3+ (x = 1,2,4 and 8 mol%). The samples formed by the complex polymerization were thoroughly characterized for physicochemical properties such powder by X-ray diffraction (XRD), and Raman and diffuse reflectance spectroscopies. First-principle calculations at the density functional theory level were performed to complement and rationalize the experimental results. An energy transfer mechanism which promote…

Phase transitionenergy transferPhotoluminescenceMaterials sciencexTb3+ (x = 124 and 8mol%) [ZrO2]lighting devicesMechanical EngineeringDopingCondensed Matter PhysicsDFT calculationssymbols.namesakeTetragonal crystal systemMechanics of Materialsphase transitionvisual_artvisual_art.visual_art_mediumsymbolsPhysical chemistryGeneral Materials ScienceDensity functional theoryCeramicDiffuse reflectionZIRCÔNIARaman spectroscopy
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