Author: Ana M. Cioran

0000000000600145

AUTHOR

Ana M. Cioran

Towards Multifunctional Materials Incorporating Elastomers and Reversible Redox-Active Fragments

This paper presents a novel and unique feature of metallacarboranes, consisting of the linkage of this redox electro-active site to a stretchable polymer. This is based on polyTHF, a known and applied material. This hybrid material has the two ends functionalized: one with the aforemen- tioned redox molecule and the other with a terminal OH group, both linked by a molecular spring. Moreover, the redox electro-active molecules can be synthesized with either cobalt (cobaltabisdicarbollide) or with iron (ferrabisdi- carbollide), species whose respective E1/2 value differs by almost 1 V. The polymerization mechanism, based on an in- termediate molecular crystal structure, is explained through a…

research product

CCDC 910884: Experimental Crystal Structure Determination

Related Article: Màrius Tarrés, Clara Viñas, Ana M. Cioran, Mikko M. Hänninen, Reijo Sillanpää, Francesc Teixidor|2014|Chem.-Eur.J.|20|15808|doi:10.1002/chem.201403424

research product

CCDC 910883: Experimental Crystal Structure Determination

Related Article: Màrius Tarrés, Clara Viñas, Ana M. Cioran, Mikko M. Hänninen, Reijo Sillanpää, Francesc Teixidor|2014|Chem.-Eur.J.|20|15808|doi:10.1002/chem.201403424

research product

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
  - PE2_1Theory of fundamental interactions
  - PE2_2 Phenomenology of fundamental interactions
  - PE2_3Experimental particle physics with accelerators
  - PE2_4Experimental particle physics without accelerators
  - PE2_6Nuclear, hadron and heavy ion physics
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  - PE2_5Classical and quantum physics of gravitational interactions
  - PE2_7Nuclear and particle astrophysics
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  - PE2_10Atomic, molecular physics
  - PE2_11Ultra-cold atoms and molecules
  - PE2_18Equilibrium and non-equilibrium statistical mechanics: steady states and dynamics
  - PE2_14Lasers, ultra-short lasers and laser physics
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  - PE2_12Optics, non-linear optics and nano-optics
  - PE2_13Quantum optics and quantum information
  - PE2_15Thermodynamics
- PE1Mathematics
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- PE3Condensed Matter Physics
  - PE3_1Structure of solids, material growth and characterisation
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  - PE11_2Engineering of metals and alloys
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  - PE11_6Engineering of carbon materials
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  - PE11_8Engineering of alternative established or emergent materials
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  - PE11_10Soft materials engineering, e.g. gels, foams, colloids
  - PE11_11Porous materials engineering, e.g. covalent-organic, metal-organic, porous aromatic frameworks
  - PE11_12Semi-conducting and magnetic materials engineering
  - PE11_13Metamaterials engineering
  - PE11_14Computational methods for materials engineering
LSLife Sciences
- LS1Molecules of Life: Biological Mechanisms, Structures and Functions
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  - LS1_14Innovative methods and modelling in molecular, structural and synthetic biology
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  - LS2_1Genetics
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  - LS2_16Innovative methods and modelling in integrative biology
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  - LS4_1Organ and tissue physiology and pathophysiology
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  - LS4_5Non-hormonal mechanisms of inter-organ and tissue communication
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  - LS4_13Other non-communicable diseases (except disorders of the nervous system and immunity-related diseases)
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  - LS3_7Mechanobiology of cells, tissues and organs
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SHSocial Sciences and Humanities
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