Author: Ana M. Cioran

0000000000600145

AUTHOR

Ana M. Cioran

showing 3 related works from this author

Towards Multifunctional Materials Incorporating Elastomers and Reversible Redox-Active Fragments

2014

This paper presents a novel and unique feature of metallacarboranes, consisting of the linkage of this redox electro-active site to a stretchable polymer. This is based on polyTHF, a known and applied material. This hybrid material has the two ends functionalized: one with the aforemen- tioned redox molecule and the other with a terminal OH group, both linked by a molecular spring. Moreover, the redox electro-active molecules can be synthesized with either cobalt (cobaltabisdicarbollide) or with iron (ferrabisdi- carbollide), species whose respective E1/2 value differs by almost 1 V. The polymerization mechanism, based on an in- termediate molecular crystal structure, is explained through a…

chemistry.chemical_classificationChemistryOrganic ChemistryMolecular springGeneral ChemistryPolymerRedoxCatalysisPolymerizationElectrophilePolymer chemistryMoleculeSurface modificationHybrid materialta116Chemistry - A European Journal

researchProduct

CCDC 910884: Experimental Crystal Structure Determination

2014

Related Article: Màrius Tarrés, Clara Viñas, Ana M. Cioran, Mikko M. Hänninen, Reijo Sillanpää, Francesc Teixidor|2014|Chem.-Eur.J.|20|15808|doi:10.1002/chem.201403424

tris(mu-acetone)-bis(55'-4-(2-[2-(dioxidan-2-id-1-yl)ethoxy]ethoxy)butyl)-11'-commo-(1-ferro-23-dicarba-closo-dodecaborane(10))-(1'-ferro-2'3'-dicarba-closo-dodecaborane(10))-di-sodiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 910883: Experimental Crystal Structure Determination

2014

Related Article: Màrius Tarrés, Clara Viñas, Ana M. Cioran, Mikko M. Hänninen, Reijo Sillanpää, Francesc Teixidor|2014|Chem.-Eur.J.|20|15808|doi:10.1002/chem.201403424

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(mu2-Acetone)-(88'-(4-(2-oxyethoxyethoxy)-n-butyl)-33'-commo-bis(3-cobalta-12-dicarba-closo-dodecaborate))-di-sodiumExperimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
  - PE2_1Theory of fundamental interactions
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  - PE2_6Nuclear, hadron and heavy ion physics
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- PE1Mathematics
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LSLife Sciences
- LS1Molecules of Life: Biological Mechanisms, Structures and Functions
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SHSocial Sciences and Humanities
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