Author: A. Berkessel

0000000000600224

AUTHOR

A. Berkessel

Supramolecular hydrogen-bonding tautomeric sulfonamido-phosphinamides: a perfect P-chirogenic memory

P-chirogenic, supramolecular hydrogen-bonding C1-symmetrical sulfonamido–phosphinamides (METAMORPhos) have been successfully prepared. They were all found to possess a characteristic prototropic equilibrium between the PIII and the PV tautomers that is slow on the NMR spectroscopic timescale. Despite the dynamic and reversible protonation of the P centre, the P-chirogenic information was found to be retained in the tautomerization process, even in a protic solvent environment. Several strategies to access the corresponding enantiopure compounds were investigated, such as diastereoselective crystallization, or enantioselective synthesis. It was possible to resolve such a class of chiral liga…

research product

CCDC 836863: Experimental Crystal Structure Determination

Related Article: F.W.Patureau, M.A.Siegler, A.L.Spek, A.J.Sandee, S.Juge, S.Aziz, A.Berkessel, J.N.H.Reek|2012|Eur.J.Inorg.Chem.||496|doi:10.1002/ejic.201100811

research product

CCDC 836862: Experimental Crystal Structure Determination

Related Article: F.W.Patureau, M.A.Siegler, A.L.Spek, A.J.Sandee, S.Juge, S.Aziz, A.Berkessel, J.N.H.Reek|2012|Eur.J.Inorg.Chem.||496|doi:10.1002/ejic.201100811

research product

PEPhysical Sciences and Engineering
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