0000000000606833
AUTHOR
Ali Sanda Bawa
Series of charge transfer complexes obtained as crystals in a confined environment
A series of charge transfer complexes (CTCs) were successfully formed by solvent free processing techniques, using the 1,2,4,5-tetracyano benzene (TCNB) as πA molecule and a series of p-dihydroquinones (H2Qs) as πD counterparts. Additionally to the classical co-evaporation techniques, we obtained CTCs in less than an hour, in a very simple confined environment, between two 100 μm – spaced glass plates. A systematical study by Raman spectroscopy on crystals highlighted the CTCs formation. Moreover, three new crystalline structures were obtained, namely TCNB-H2Q that crystallizes in columns connected to each other by H-bonds, while with the methoxy- and dimethoxy-H2Qs the CTC forms crystals w…
CCDC 1994293: Experimental Crystal Structure Determination
Related Article: Ali Sanda Bawa, Rita Meunier-Prest, Yoann Rousselin, Jean-Pierre Couvercelle, Christine Stern, Bernard Malézieux, Marcel Bouvet|2021|CrystEngComm|23|6418|doi:10.1039/D1CE00929J
CCDC 2063384: Experimental Crystal Structure Determination
Related Article: Ali Sanda Bawa, Rita Meunier-Prest, Yoann Rousselin, Jean-Pierre Couvercelle, Christine Stern, Bernard Malézieux, Marcel Bouvet|2021|CrystEngComm|23|6418|doi:10.1039/D1CE00929J
CCDC 1994294: Experimental Crystal Structure Determination
Related Article: Ali Sanda Bawa, Rita Meunier-Prest, Yoann Rousselin, Jean-Pierre Couvercelle, Christine Stern, Bernard Malézieux, Marcel Bouvet|2021|CrystEngComm|23|6418|doi:10.1039/D1CE00929J