Author: Nicolás Veiga

0000000000613817

AUTHOR

Nicolás Veiga

showing 3 related works from this author

Exchange coupling in a thiocyanato-bridged copper(II) chain: Computational approach to magnetostructural correlations

2021

Abstract In this article we report the synthesis and magneto-structural characterization of two new copper(II) compounds with thiocyanato and methyl(2-pyridil) ketone oxime (mpkOH), namely [Cu(NCS)(mpkO)(mpkOH)] (1) and [Cu(µ-NCS)(NCS)(mpkOH)]n (2). Compound 1 is a mononuclear complex that crystallizes as discrete units. Conversely, compound 2 is a single equatorial-axial end-to-end thiocyanato bridged polymeric chain of Cu(II) with the oxime as a co-ligand. The coordination geometry around the Cu(II) centers is distorted square pyramidal for 1 and 2. The magnetic susceptibility data for 2 reveal weak intrachain antiferromagnetic coupling, with J value −0.74(3) cm−1 and g = 2.10(1). The ap…

chemistry.chemical_classificationKetoneChemistrychemistry.chemical_elementOximeCopperMagnetic susceptibilitySquare pyramidal molecular geometryInorganic Chemistrychemistry.chemical_compoundBipyramidCrystallographyFerromagnetismMaterials ChemistryPhysical and Theoretical ChemistryCoordination geometryPolyhedron

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CCDC 864758: Experimental Crystal Structure Determination

2021

Related Article: Lorena Martínez, Nicolás Veiga, Carla Bazzicalupi, Antonio Bianchi, Francesc Lloret, Carlos Kremer, Raúl Chiozzone|2021|Polyhedron|208|115406|doi:10.1016/j.poly.2021.115406

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-isothiocyanato)-(isothiocyanato)-(N-[1-(pyridin-2-yl)ethylidene]hydroxylamine)-copper(ii)]Experimental 3D Coordinates

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CCDC 2073463: Experimental Crystal Structure Determination

2021

Related Article: Lorena Martínez, Nicolás Veiga, Carla Bazzicalupi, Antonio Bianchi, Francesc Lloret, Carlos Kremer, Raúl Chiozzone|2021|Polyhedron|208|115406|doi:10.1016/j.poly.2021.115406

{N-[1-(pyridin-2-yl)ethylidene]hydroxylamine}-{N-[1-(pyridin-2-yl)ethylidene]oxylaminato}-(isothiocyanato)-copperSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

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