Expanding the NUIG MOF family: synthesis and characterization of new MOFs for selective CO2 adsorption, metal ion removal from aqueous systems, and drug delivery applications
Metal organic frameworks (MOFs) have attracted considerable attention in recent years due to their use in a wide range of environmental, industrial and biomedical applications. The employment of benzophenone-4,4'-dicarboxylic acid (bphdcH2) in MOF chemistry provided access to the 3D mixed metal MOFs [CoNa2(bphdc)2(DMF)2]n (NUIG2) and [ZnK2(bphdc)2(DMF)2]n (NUIG3), and the 2D homometallic MOF [Co2(OH)(bphdcH)2(DMF)2(H2O)2]n(OH)·DMF (1·DMF). 1·DMF is based on a dinuclear SBU and consists of interpenetrating networks with an sql topology. Dc magnetic susceptibility studies were carried out in 1·DMF and revealed the presence of weak antiferomagnetic exchange interactions between the metal centr…
CCDC 2061983: Experimental Crystal Structure Determination
Related Article: Meghan Winterlich, Darragh McHugh, Evan O'Toole, Katerina Skordi, Ciaran O'Malley, Rana Sanii, Anastasios Tasiopoulos, Andrea Erxleben, Júlia Mayans, Liam Morrison, Patrick McArdle, Michael J. Zaworotko, Emmanuel Tylianakis, George Froudakis, Constantina Papatriantafyllopoulou|2021|Dalton Trans.|50|6997|doi:10.1039/D1DT00940K