0000000000624441

AUTHOR

Michael Krisch

0000-0001-7423-1715

showing 2 related works from this author

Probing the thermal stability and the decomposition mechanism of a magnesium-fullerene polymer via X-ray Raman spectroscopy, X-ray diffraction and mo…

2016

International audience; We report the microscopic view of the thermal structural stability of the magnesium intercalated fullerene polymer Mg2C60. With the application of X-ray Raman spectroscopy and X-ray diffraction, we study in detail the decomposition pathways of the polymer system upon annealing at temperatures between 300 and 700 degrees C. We show that there are at least two energy scales involved in the decomposition reaction. Intermolecular carbon bonds, which are responsible for the formation of a 2D fullerene polymer, are broken with a relatively modest thermal energy, while the long-range order of the original polymer remains intact. With an increased thermal energy, the crystal…

Phase transitionFullerene116 Chemical sciencesGeneral Physics and Astronomy02 engineering and technologySALTSPRESSURE010402 general chemistry01 natural sciences7. Clean energy114 Physical sciencessymbols.namesakeSCATTERING[CHIM]Chemical SciencesThermal stabilityPhysical and Theoretical ChemistryMagnesium ionQuantitative Biology::BiomoleculesChemistryIntermolecular force021001 nanoscience & nanotechnologyFULLERIDES0104 chemical sciencesX-ray crystallographysymbolsPhysical chemistryDensity functional theory0210 nano-technologyRaman spectroscopyC-60
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InN thin film lattice dynamics by grazing incidence inelastic x-ray scattering.

2011

Achieving comprehensive information on thin film lattice dynamics so far has eluded well established spectroscopic techniques. We demonstrate here the novel application of grazing incidence inelastic x-ray scattering combined with ab initio calculations to determine the complete elastic stiffness tensor, the acoustic and low-energy optic phonon dispersion relations of thin wurtzite indium nitride films. Indium nitride is an especially relevant example, due to the technological interest for optoelectronic and solar cell applications in combination with other group III nitrides.

Indium nitrideMaterials sciencePhononGeneral Physics and AstronomyPhysics::Optics:Matemàtiques i estadística::Matemàtica discreta::Combinatòria [Àrees temàtiques de la UPC]Nitridechemistry.chemical_compoundCondensed Matter::Materials ScienceWurtzite alnOpticsAb initio quantum chemistry methodsDispersion relationThin filmHexagonal InNPseudopotentialsWurtzite crystal structureCondensed matter physicsbusiness.industryScatteringLattice dynamics:Enginyeria electrònica [Àrees temàtiques de la UPC]Reticles Teoria dechemistryFISICA APLICADAbusinessSpectroscopic techniquesDinàmica reticularFundamental-band gapPhysical review letters
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