0000000000626050
AUTHOR
Mamadou Ndiaye
Bromide hydrogen oxalate salts with the diprotonated 1,4-diazabicyclo[2.2.2]octane counterion
Abstract Two new salts composed of the diprotonated 1,4-diazabicyclo[2.2.2]octane (DABCO) molecule as the cations and bromide and hydrogen oxalate as the anions have been isolated and structurally characterized by X-ray diffraction analysis. The salt [DABCOH2]{[HC2O4][Br]} (1) crystallizes in the orthorhombic system, space group P212121 with a = 9.0809(7), b = 9.5156(7), c = 12.3558(9) Å, V = 1067.67(14) Å3 and Z = 4. The salt [DABCOH2]2{[HC2O4][Br]3}·H2O (2) crystallizes in the orthorhombic system, space group Pnma with a = 26.6554(17), b = 7.3711(4), c = 10.7421(7) Å, V = 2110.6(2) Å3 and Z = 4. The compounds were prepared from ethanolic solutions of [DABCOH2][HC2O4]2 (L 1 ) and ZnBr2 in …
CCDC 1835271: Experimental Crystal Structure Determination
Related Article: Mamadou Ndiaye, Mouhamadou Birame Diop, Abdoulaye Samb, Libasse Diop, Allen G. Oliver, Laurent Plasseraud|2020|Zeitschrift fuer Naturforschung, Teil B. Anorganische Chemie, Organische Chemie|75|815 |doi:10.1515/znb-2020-0097
CCDC 1835272: Experimental Crystal Structure Determination
Related Article: Mamadou Ndiaye, Mouhamadou Birame Diop, Abdoulaye Samb, Libasse Diop, Allen G. Oliver, Laurent Plasseraud|2020|Zeitschrift fuer Naturforschung, Teil B. Anorganische Chemie, Organische Chemie|75|815 |doi:10.1515/znb-2020-0097