0000000000628085

AUTHOR

Mateusz Penkala

0000-0001-8949-0322

showing 7 related works from this author

Heterobimetallic Oxalate‐Bridged M II Re IV (M = Zn, Cu, Ni, Co and Mn) Complexes Incorporating Bis(3,5‐dimethylpyrazol‐1‐yl)methane: Synthesis and M…

2016

Five oxalato-bridged heterobimetallic compounds of general formula [ReCl4(ox)M(bdmpzm)2].2MeCN [ox = oxalate, bdmpzm = bis(3,5-dimethylpyrazol-1-yl)methane and M = Zn (1),Cu (2), Ni (3), Co (4) and Mn (5)] have been successfully synthesized in self-assembly reactions of the [ReCl4(ox)]2- metalloligand with the coordinatively unsaturated [M(bdmpzm)2]2+ complex generated in situ by the reaction of the suitable metal(II) salt with the bdmpzm ligand. 1-5 are isostructural compounds whose crystal structures consist of neutral heterodinuclear [ReCl4(ox)M(bdmpzm)2] units and free acetonitrile molecules. The magnetic properties of 1-5 were investigated in the temperature range 2.0-300 K. The nature…

010405 organic chemistryLigandInorganic chemistryCrystal structure010402 general chemistry01 natural sciencesOxalate0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryTransition metalX-ray crystallographyMoleculeIsostructuralAcetonitrileEuropean Journal of Inorganic Chemistry
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Synthesis, crystal structure and magnetic properties of H2tppz[ReCl6] and [Cu(bpzm)2(μ-Cl)ReCl3(μ-ox)Cu(bpzm)2(μ-ox)ReCl3(μ-Cl)]n.

2015

Two new Re(iv) compounds of formulae H2tppz[ReCl6] (1) and [Cu(bpzm)2(μ-Cl)ReCl3(μ-ox)Cu(bpzm)2(μ-ox)ReCl3(μ-Cl)]n (2) [tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine and bpzm = bis(pyrazolyl-1-yl)methane] have been prepared and their crystal structures determined by X-ray diffraction on single crystals. Compound 1 is a mononuclear species whose structure consists of octahedral hexachlororhenate(iv) anions and diprotonated H2tppz(2+) cations which are arranged in the unit cell as alternating anionic and cationic layers, held together by electrostatic forces. The structure of 2 is made up of alternating [Cu(1)(bpzm)2](2+) and [(ox)ReCl3(μ-Cl)Cu(2)(bpzm)2(μ-Cl)ReCl3(ox)](2-) entities interlinked …

Inorganic Chemistrychemistry.chemical_compoundCrystallographyDenticityOctahedronFerromagnetismPyrazineChemistryAntiferromagnetismCrystal structureAtmospheric temperature rangeOxalateDalton transactions (Cambridge, England : 2003)
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CCDC 1471985: Experimental Crystal Structure Determination

2016

Related Article: Izabela Gryca, Joanna Palion-Gazda, Barbara Machura, Mateusz Penkala, Francesc Lloret and Miguel Julve|2016|Eur.J.Inorg.Chem.||5418|doi:10.1002/ejic.201601004

(mu-oxalato)-bis(1-((35-dimethyl-1H-pyrazol-1-yl)methyl)-35-dimethyl-1H-pyrazole)-tetrachloro-rhenium(iv)-manganese(ii) acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1471984: Experimental Crystal Structure Determination

2016

Related Article: Izabela Gryca, Joanna Palion-Gazda, Barbara Machura, Mateusz Penkala, Francesc Lloret and Miguel Julve|2016|Eur.J.Inorg.Chem.||5418|doi:10.1002/ejic.201601004

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-oxalato)-bis(1-((35-dimethyl-1H-pyrazol-1-yl)methyl)-35-dimethyl-1H-pyrazole)-tetrachloro-rhenium(iv)-copper(ii) acetonitrile solvateExperimental 3D Coordinates
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CCDC 1471982: Experimental Crystal Structure Determination

2016

Related Article: Izabela Gryca, Joanna Palion-Gazda, Barbara Machura, Mateusz Penkala, Francesc Lloret and Miguel Julve|2016|Eur.J.Inorg.Chem.||5418|doi:10.1002/ejic.201601004

Space GroupCrystallography(mu-oxalato)-bis(1-((35-dimethyl-1H-pyrazol-1-yl)methyl)-35-dimethyl-1H-pyrazole)-tetrachloro-rhenium(iv)-cobalt(ii) acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1471986: Experimental Crystal Structure Determination

2016

Related Article: Izabela Gryca, Joanna Palion-Gazda, Barbara Machura, Mateusz Penkala, Francesc Lloret and Miguel Julve|2016|Eur.J.Inorg.Chem.||5418|doi:10.1002/ejic.201601004

(mu-oxalato)-bis(1-((35-dimethyl-1H-pyrazol-1-yl)methyl)-35-dimethyl-1H-pyrazole)-tetrachloro-rhenium(iv)-nickel(ii) acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1471983: Experimental Crystal Structure Determination

2016

Related Article: Izabela Gryca, Joanna Palion-Gazda, Barbara Machura, Mateusz Penkala, Francesc Lloret and Miguel Julve|2016|Eur.J.Inorg.Chem.||5418|doi:10.1002/ejic.201601004

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-oxalato)-bis(1-((35-dimethyl-1H-pyrazol-1-yl)methyl)-35-dimethyl-1H-pyrazole)-tetrachloro-rhenium(iv)-zinc(ii) acetonitrile solvateExperimental 3D Coordinates
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