0000000000635151

AUTHOR

Sebastian Leubner

0000-0003-2644-0568

showing 3 related works from this author

Expanding the Variety of Zirconium‐based Inorganic Building Units for Metal–Organic Frameworks

2019

Two new zirconium-based metal-organic frameworks with the composition [Zr6 O4 (OH)4 (OAc)6 (BDC)3 ] (CAU-26) and [Zr5 O4 (OH)4 (OAc)4 (BDC)2 ] (CAU-27) are reported, which were synthesized from acetic acid, a rarely utilized but green and sustainable solvent (BDC2- : 1,4-benzenedicarboxylate). Structure determination aided by automated electron diffraction tomography revealed that CAU-26 is composed of layers of well-known {Zr6 O8 } clusters interconnected by terephthalate ions. In contrast CAU-27 exhibits a three-dimensional structure with a so far unknown type of one-dimensional inorganic building unit (IBU), which can be rationalized as condensed polyhedron-sharing chains of {Zr6 O8 } cl…

Green chemistryMaterials scienceChemistry MultidisciplinaryCATALYZED BORYLATIONchemistry.chemical_element010402 general chemistryHIGHLY EFFICIENTBorylation01 natural sciencesTOXICITYCatalysisCatalysisAUTOMATED DIFFRACTION TOMOGRAPHYPolymer chemistryMoleculeZR-MOFGreen ChemistryZirconiumScience & TechnologySTABILITY010405 organic chemistryDirect C-H borylationGeneral ChemistryGeneral MedicineElectron DiffractionORGANOSILICA0104 chemical sciencesSolventChemistrychemistryPhysical SciencesARENESMetal-organic frameworkChemical stabilityZirconiumCLUSTERSMetal-organic FrameworksGREEN SYNTHESISAngewandte Chemie
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CCDC 1880628: Experimental Crystal Structure Determination

2019

Related Article: Sebastian Leubner, Haishuang Zhao, Niels Van Velthoven, Mickael Henrion, Helge Reinsch, Dirk De Vos, Ute Kolb, Norbert Stock|2019|Angew.Chem.,Int.Ed.|58|10995|doi:10.1002/anie.201905456

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-benzene-14-dicarboxylato)-tetrakis(mu-oxido)-tetrakis(mu-hydroxo)-tetrakis(mu-acetato)-penta-zirconium(iv) hydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1880629: Experimental Crystal Structure Determination

2019

Related Article: Sebastian Leubner, Haishuang Zhao, Niels Van Velthoven, Mickael Henrion, Helge Reinsch, Dirk De Vos, Ute Kolb, Norbert Stock|2019|Angew.Chem.,Int.Ed.|58|10995|doi:10.1002/anie.201905456

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-[11'-biphenyl]-44'-dicarboxylato)-tetrakis(mu-hydroxo)-tetrakis(mu-oxido)-tetrakis(mu-acetato)-penta-zirconium(iv) hydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
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