0000000000639742

AUTHOR

Nicholas H. Rees

showing 8 related works from this author

Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi-Lability.

2021

We report on the synthesis of a distannyne supported by a pincer ligand bearing pendant amine donors that is capable of reversibly activating E–H bonds at one or both of the tin centres through dissociation of the hemi-labile N–Sn donor/acceptor interactions. This chemistry can be exploited to sequentially (and reversibly) assemble mixed-valence chains of tin atoms of the type ArSn{Sn(Ar)H} n SnAr ( n = 1, 2). The experimentally observed (decreasing) propensity towards chain growth with increasing chain length can be rationalized both thermodynamically and kinetically by the electron-withdrawing properties of the –Sn(Ar)H– backbone units generated via oxidative addition. peerReviewed

oxidative additionchemistry.chemical_element010402 general chemistry01 natural sciencesCatalysisDissociation (chemistry)Reductive eliminationreversibilityNucleophilic aromatic substitutiontinPolymer chemistryPincer ligandkemiallinen synteesiChemistry010405 organic chemistryreductive eliminationliganditkompleksiyhdisteetGeneral ChemistryGeneral MedicineAcceptorOxidative addition3. Good health0104 chemical scienceshemi-labile ligandorgaaniset tinayhdisteettinaAmine gas treatingTinAngewandte Chemie (International ed. in English)
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CCDC 2094341: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

Space GroupCrystallographyCrystal SystemCrystal Structure(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-(formato)-tin (26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-chloro-tinCell ParametersExperimental 3D Coordinates
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CCDC 2094344: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

Space GroupCrystallography(mu-carbonato)-bis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-di-tinCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2094340: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

Space GroupCrystallographyCrystal Systembis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl-C)-bis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl-CN)-tetra-tin diethyl ether solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2094342: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-hydrido-tri-tin pentane solvateExperimental 3D Coordinates
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CCDC 2094346: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

Space GroupCrystallographyCrystal SystemCrystal Structure(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-iodo-tinCell ParametersExperimental 3D Coordinates
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CCDC 2094343: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl-CN)-bis(26-bis{[bis(propan-2-yl)amino]methyl}phenyl-C)-dihydrido-tetra-tin hexane solvateExperimental 3D Coordinates
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CCDC 2094345: Experimental Crystal Structure Determination

2021

Related Article: Alexa Caise, Agamemnon E. Crumpton, Petra Vasko, Jamie Hicks, Caitilín McManus, Nicholas H. Rees, Simon Aldridge|2022|Angew.Chem.,Int.Ed.|61|e202114926|doi:10.1002/anie.202114926

(26-bis{[bis(propan-2-yl)amino]methyl}phenyl)-bromo-tinSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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