0000000000640322

AUTHOR

Simon Steike

showing 11 related works from this author

Di-, Tri-, and Tetra(pentafluorophenyl) Derivatives for Oligotopic Anion−π Interactions

2013

The present study describes a series of pentafluorobenzyl ammonium salts with two, three, or four C6F5 units in order to investigate simultaneous interactions of several perfluorinated arenes with anions in the crystalline state. Most of the structures show multiple anion-π contacts. However, only 6·2HI reveals an effective encapsulation of the iodide ion by the aromatic units. For comparison, the structure of 4b is investigated because it offers two π-systems with inverse charge distribution to a bromide anion. Only the electron-deficient π-system of the pentafluorophenyl group interacts with the anion.

biologyChemistryChemieCharge densitybiology.organism_classificationMedicinal chemistryIonInorganic ChemistryIodide ionchemistry.chemical_compoundBromideTetraAmmoniumPhysical and Theoretical Chemistryta116Inorganic Chemistry
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CCDC 967090: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersNNN'N'-tetramethyl-NN'-bis(pentafluorobenzyl)ethane-12-diaminium sulfate ethyl acetate methanol solvate trihydrateExperimental 3D Coordinates
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CCDC 967091: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

Space GroupCrystallographyNNN'N'-tetramethyl-NN'-bis(pentafluorobenzyl)propane-13-diaminium dibromide monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 967092: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates1-benzyl-4-(pentafluorobenzyl)-14-diazoniabicyclo[2.2.2]octane dibromide ethanol solvate
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CCDC 967093: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

Space GroupCrystallography147-tris(pentafluorobenzyl)-147-triazonaneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 967097: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K

Space GroupCrystallographyNNN'N'-tetramethyl-NN'-bis(pentafluorobenzyl)ethane-12-diaminium dibromide dimethyl sulfoxide solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 967088: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersNN-dimethyl-NN-bis(pentafluorobenzyl)ammonium bromideExperimental 3D Coordinates
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CCDC 967089: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Arto Valkonen, Kari Rissanen|2015|Chemical Science|6|354|doi:10.1039/C4SC02762K

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D CoordinatesNNN'N'-tetramethyl-NN'-bis(pentafluorobenzyl)ethane-12-diaminium bromide chloride dimethyl sulfoxide solvate
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CCDC 967095: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

NNN'N'-tetrakis(pentafluorobenzyl)ethane-12-diamineSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 967096: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

Space GroupCrystallographyNNN'N'-tetrakis(pentafluorobenzyl)ethane-12-diaminium diiodide chloroform solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 967094: Experimental Crystal Structure Determination

2013

Related Article: Michael Giese, Markus Albrecht, Simon Steike, Anton Ackermann, Arto Valkonen, and Kari Rissanen|2013|Inorg.Chem.|52|7666|doi:10.1021/ic4008087

Space GroupCrystallographyCrystal System1-methyl-147-tris(pentafluorobenzyl)-147-triazonan-1-ium iodide monohydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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