0000000000643326

AUTHOR

Niklas Löffler

showing 3 related works from this author

Refining the temperature dependence of the oxygen and clumped isotopic compositions of structurally bound carbonate in apatite

2019

Abstract Clumped isotope data from carbonated apatite from in vivo and in vitro samples are presented to refine the relationship between mineral growth temperature and carbonate clumped isotopic composition (Δ47). Δ47, δ18O and δ13C data were obtained from phosphoric acid digestion (T = 110 °C) of chemically untreated teeth from an African elephant, Greenland sharks, sand tiger sharks and synthetic apatites. These data cover a temperature range between 1 °C and 80 °C and enlarge the calibration dataset presented in Wacker et al. (2016) by a factor of five. Taxon-specific analyses of tooth enamel(oid) and dentine reveal that both tissues show identical Δ47 values even though the content of o…

Calcitefood.ingredient010504 meteorology & atmospheric sciencesChemistryδ18OAragoniteAnalytical chemistryFractionationengineering.material010502 geochemistry & geophysics01 natural sciencesApatiteIsotopes of oxygenCarcharodonchemistry.chemical_compoundfoodGeochemistry and Petrologyvisual_artvisual_art.visual_art_mediumengineeringCarbonate14. Life underwater0105 earth and related environmental sciencesGeochimica et Cosmochimica Acta
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Clumped isotope thermometry of carbonate-bearing apatite: Revised sample pre-treatment, acid digestion, and temperature calibration

2016

Abstract It has recently been shown that the clumped isotopic composition (Δ47) of carbonate-bearing hydroxyapatite (CHAP) from teeth and bones reveals important information about the body temperature of vertebrates (Eagle et al., 2010, 2011). In this study we reinvestigate the temperature dependence of Δ47 in CHAP, extending the temperature range from 2 to 59 °C. In addition, the effects of chemical pre-treatment of CHAP on its bulk and clumped isotopic composition are studied. CHAP is best reacted with phosphoric acid at 90 to 110 °C minimizing the potential of evolved CO2 or reaction intermediates to re-equilibrate with traces of water in the acid environment. Reaction at 110 °C ensures …

CalciteEnamel paintAragonite010401 analytical chemistryAnalytical chemistryMineralogyGeologyAtmospheric temperature rangeengineering.material010502 geochemistry & geophysicsTooth enamel01 natural sciencesApatite0104 chemical scienceschemistry.chemical_compoundmedicine.anatomical_structurechemistryGeochemistry and Petrologyvisual_artmedicinevisual_art.visual_art_mediumengineeringCarbonatePhosphoric acid0105 earth and related environmental sciencesChemical Geology
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Data for: Refining the temperature dependence of the oxygen and clumped isotopic compositions of structurally bound carbonate in apatite

2020

Compilation of all measured and calculated data from equilibrated gases and empirical transfer functions (I.), standard (II.) and sample (III.) measurements including δ47 and raw Δ47 values. Comparison of [Brand] processed Δ47 values of ETH-1, ETH-2, and ETH-3 with Δ47 values from prior studies (IV.).The sample materials (III.) are: Synthetic hydroxyapatites, tooth enamel(oid) and dentine from African elephant (Loxodonta africana) and Greenland shark (Somniosus microcephalus), sand tiger shark tooth dentine (Carcharias taurus), and megatooth shark tooth enameloid (Carcharodon megalodon). THIS DATASET IS ARCHIVED AT DANS/EASY, BUT NOT ACCESSIBLE HERE. TO VIEW A LIST OF FILES AND ACCESS THE F…

Analytical GeochemistryIsotope GeochemistryTemperatureInterdisciplinary sciencesOtherPaleobiologySharkStable Isotopes TechniqueElephantPaleoenvironmental Reconstruction
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