0000000000651394

AUTHOR

Tejas S. Sherkar

showing 2 related works from this author

Improving Perovskite Solar Cells: Insights From a Validated Device Model

2017

To improve the efficiency of existing perovskite solar cells (PSCs), a detailed understanding of the underlying device physics during their operation is essential. Here, a device model has been developed and validated that describes the operation of PSCs and quantitatively explains the role of contacts, the electron and hole transport layers, charge generation, drift and diffusion of charge carriers and recombination. The simulation to the experimental data of vacuum-deposited CH3NH3PbI3 solar cells over multiple thicknesses has been fit and the device behavior under different operating conditions has been studied to delineate the influence of the external bias, charge-carrier mobilities, e…

Solar cellsMaterials sciencePassivationNanotechnology02 engineering and technology010402 general chemistry01 natural sciencesPolymer solar celllaw.inventionlawSolar cellGeneral Materials SciencePerovskite (structure)Theory of solar cellsRenewable Energy Sustainability and the Environmentbusiness.industryEnergy conversion efficiencyHybrid solar cell021001 nanoscience & nanotechnology0104 chemical sciencesPEROVSKITESOptoelectronicsCharge carrierPerovskite Solar CellsDEVICE PHYSICS0210 nano-technologybusinessAdvanced Energy Materials
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Recombination in Perovskite Solar Cells

2017

Trap-assisted recombination, despite being lower as compared with traditional inorganic solar cells, is still the dominant recombination mechanism in perovskite solar cells (PSCs) and limits their efficiency. We investigate the attributes of the primary trap assisted recombination channels (grain boundaries and interfaces) and their correlation to defect ions in PSCs. We achieve this by using a validated device model to fit the simulations to the experimental data of efficient vacuum-deposited p-i-n and n-i-p CH3NH3PbI3 solar cells, including the light intensity dependence of the open circuit voltage and fill factor. We find that, despite the presence of traps at interfaces and grain bounda…

Materials scienceLetterEFFICIENCYMETHYLAMMONIUM LEAD IODIDEMIGRATIONEnergy Engineering and Power TechnologyNanotechnology02 engineering and technologyQuantum dot solar cell010402 general chemistryFILMS01 natural sciencesIonMaterials ChemistryORGANOMETAL TRIHALIDE PEROVSKITEVOLTAGEHYSTERESISPerovskite (structure)Theory of solar cellsRenewable Energy Sustainability and the EnvironmentHybrid solar cellELECTRICAL-PROPERTIES021001 nanoscience & nanotechnologySURFACE-DEFECTSTRANSPORT0104 chemical sciencesLight intensityFuel TechnologyChemistry (miscellaneous)Chemical physicsGrain boundary0210 nano-technologyRecombinationACS Energy Letters
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