0000000000659610
AUTHOR
G.c. Papavassiliou
Hybrid Molecular Materials Based upon Organic π-Electron Donors and Inorganic Metal Complexes. Conducting Salts of Bis(ethylenediseleno)tetrathiafulvalene (BEST) with the Octahedral Anions Hexacyanoferrate(III) and Nitroprusside
Abstract The synthesis, structure and physical characterization of three new radical salts formed by the organic donor bis(ethylenediseleno)tetrathiafulvalene (BEDS-TTF or BEST) and the paramagnetic hexacyanoferrate(III) anion [Fe(CN)6]3− or the photochromic nitroprusside anion [Fe(CN)5NO]2− are reported: (BEST)4[Fe(CN)6] (1), (BEST)3[Fe(CN)6]2·H2O (2) and (BEST)2[Fe(CN)5NO] (3). Salts 1 and 3 show a layered structure with alternating organic (β–type packing) and inorganic slabs. Salt 2 shows an original interpenetrated structure probably due to the unprecedented presence of (BEST)2+ dications. The three salts are semiconductors although salt 1 exhibits a high room temperature conductivity …
CCDC 183751: Experimental Crystal Structure Determination
Related Article: M.Clemente-Leon, E.Coronado, J.R.Galan-Mascaros, C.Gimenez-Saiz, C.J.Gomez-Garcia, J.M.Fabre, G.A.Mousdis, G.C.Papavassiliou|2002|J.Solid State Chem.|168|616|doi:10.1006/jssc.2002.9759
CCDC 183749: Experimental Crystal Structure Determination
Related Article: M.Clemente-Leon, E.Coronado, J.R.Galan-Mascaros, C.Gimenez-Saiz, C.J.Gomez-Garcia, J.M.Fabre, G.A.Mousdis, G.C.Papavassiliou|2002|J.Solid State Chem.|168|616|doi:10.1006/jssc.2002.9759
CCDC 183750: Experimental Crystal Structure Determination
Related Article: M.Clemente-Leon, E.Coronado, J.R.Galan-Mascaros, C.Gimenez-Saiz, C.J.Gomez-Garcia, J.M.Fabre, G.A.Mousdis, G.C.Papavassiliou|2002|J.Solid State Chem.|168|616|doi:10.1006/jssc.2002.9759