Bromine degassing in basaltic volcanic systems

Mapping fumarolic fields in volcanic areas: A methodological approach based on the case study of La Fossa cone, Vulcano island (Italy)

Abstract Changes in the activity state of a volcano can be inferred by monitoring the steam flux from fumarolic fields, in terms of 4D (x, y, z, time) variations in temperature and extension of the zone. During the last decades, several studies in this field have been conducted worldwide, and at Vulcano island (Italy) in particular. Both direct and remotely sensed measurements have been used for identifying thermally anomalous areas, but the possible role of the hydrothermal alteration of volcanic products, producing a sealing effect that obscures the surface thermal evidence of fumarolic activity, have never been explored. The novelty of the present study, carried out at La Fossa cone (Vul…

A new set of standards for in–situ measurement of bromine abundances in natural silicate glasses: Application to SR-XRF, LA-ICP-MS and SIMS techniques

Measuring the low bromine abundances in Earth's materials remains an important challenge in order to constrain the geodynamical cycle of this element. Suitable standard materials are therefore required to establish reliable analytical methods to quantify Br abundances. In this study we characterise 21 Br-doped glasses synthesized from natural volcanic rocks of mafic to silicic compositions, in order to produce a new set of standards for Br analyses using various techniques. The nominal Br contents (amounts of Br loaded in the experimental samples) of 15 of 21 glasses were confirmed within 20% by instrumental neutron activation analysis (INAA). Using this new set of standards, we compare thr…