0000000000672469
AUTHOR
Gourab Kundu
Selective Synthesis of Z -Silyl Enol Ethers via Ni-Catalyzed Remote Functionalization of Ketones
Journal of the American Chemical Society : JACS 143(22), 8375-8380 (2021). doi:10.1021/jacs.1c01797
A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air
Abstract We report a new air‐stable PdI dimer, [Pd(μ‐I)(PCy2 tBu)]2, which triggers E‐selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C−C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C−Br, C−OTf/OFs, and C−Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C−OTf.
CCDC 2009560: Experimental Crystal Structure Determination
Related Article: Sinem Guven, Gourab Kundu, Andrea Weßels, Jas S. Ward, Kari Rissanen, Franziska Schoenebeck|2021|J.Am.Chem.Soc.|143|8375|doi:10.1021/jacs.1c01797
CCDC 2009558: Experimental Crystal Structure Determination
Related Article: Sinem Guven, Gourab Kundu, Andrea Weßels, Jas S. Ward, Kari Rissanen, Franziska Schoenebeck|2021|J.Am.Chem.Soc.|143|8375|doi:10.1021/jacs.1c01797
CCDC 2008108: Experimental Crystal Structure Determination
Related Article: Gourab Kundu, Theresa Sperger, Kari Rissanen, Franziska Schoenebeck|2020|Angew.Chem.,Int.Ed.|59|21930|doi:10.1002/anie.202009115
CCDC 2009557: Experimental Crystal Structure Determination
Related Article: Sinem Guven, Gourab Kundu, Andrea Weßels, Jas S. Ward, Kari Rissanen, Franziska Schoenebeck|2021|J.Am.Chem.Soc.|143|8375|doi:10.1021/jacs.1c01797
CCDC 2009559: Experimental Crystal Structure Determination
Related Article: Sinem Guven, Gourab Kundu, Andrea Weßels, Jas S. Ward, Kari Rissanen, Franziska Schoenebeck|2021|J.Am.Chem.Soc.|143|8375|doi:10.1021/jacs.1c01797