Purely Spectroscopic Determination of the Spin Hamiltonian Parameters in High-Spin Six-Coordinated Cobalt(II) Complexes with Large Zero-Field Splitting.
Accurate determination of the spin Hamiltonian parameters in transition-metal complexes with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and spectroscopic properties of high-spin transition metal complexes. Recent critical papers have convincingly shown that previous determinations of these parameters, based only on the magnetic data, have low accuracy and reliability. A combination of X-band electron paramagnetic resonance (EPR) spectroscopy and SQUID magnetometry seems to be a more convincing and accurate approach. However, even in this case, the accuracy of the determination of the spin Hamiltonian parameters is strongly limited. In this work, we propose …
CCDC 1911055: Experimental Crystal Structure Determination
Related Article: Eugenii Ya. Misochko, Alexander V. Akimov, Denis V. Korchagin, Joscha Nehrkorn, Mykhaylo Ozerov, Andrew V. Palii, Juan Modesto Clemente-Juan, Sergey M. Aldoshin|2019|Inorg.Chem.|58|16434|doi:10.1021/acs.inorgchem.9b02195