0000000000676357
AUTHOR
Teresa Cusati
showing 2 related works from this author
Competition between inter- and intra- molecular energy exchanges in a simple quantum model of a dimer
2006
Abstract We propose a fully quantum model to describe the dynamics of a possible radiationless energy transfer process between identical and nearly localized molecules or monomers coupled through a dipole–dipole term. The system is studied as an environmentally isolated dimeric pair and we find that its dynamics exhibits a competition between the process ruling out the transfer of energy among different degrees of freedom of a given monomer and the one steering the intermolecular passage of excitations from a monomer to the other one. Such a competition is quantitatively characterized investigating on the temporal behaviour of quantum covariances of some couples of appropriate observables h…
Quantum signatures in the dynamics of two dipole-dipole interacting soft dimers
2006
The quantum covariances of physically transparent pairs of observables relative to two dimers hosted in a solid matrix are exactly investigated in the temporal domain. Both dimers possess fermionic and bosonic degrees of freedom and are dipolarly coupled. We find out and describe clear signatures traceable back to the presence and persistence of quantum coherence in the time evolution of the system. Manifestations of a competition between intramolecular and intermolecular energy migration mechanisms are brought to light. The experimental relevance of our results is briefly commented.