0000000000677998
AUTHOR
Santo Lanza
Synthesis, solution behaviour and potential anticancer activity of new trinuclear organometallic palladium(II) complex of S-1-phenylethyl dithiooxamide: Comparison with the trinuclear heterobimetallic platinum(II) analogue
Abstract Addition of H2R2DTO (R = {S}-1-phenylethyl and DTO = dithiooxamide) to the bis(benzonitrile)palladium(II) chloride complex in chloroform afforded the mononuclear Pd(DTO)2·2HCl complex. The complex treated with NaHCO3 for removing of HCl and then reacted with [Pd(ƞ3-allyl)(µ-Cl)]2 for preparation of a new trimetallic organopalladium(II) complex. The molecular structure of the trimetallic complex was determined by X-ray diffraction indicating a planar geometry around each palladium center. Also, variable temperature spectroscopy for this complex was performed in CDCl3 in the range 298–390 K, and simulations of the dynamic spectra were performed using the gNMR program. A comparison be…
CCDC 1824552: Experimental Crystal Structure Determination
Related Article: Banafshe Askari, Hadi Amiri Rudbari, Nicola Micale, Tanja Schirmeister, Antonino Giannetto, Santo Lanza, Giuseppe Bruno, Valiallah Mirkhani|2019|Polyhedron|164|195|doi:10.1016/j.poly.2019.02.049