0000000000681109
AUTHOR
Nathália R. De Campos
Polymorphic Derivatives of NiII and CoII Mesocates with 3D Networks and “Brick and Mortar” Structures: Preparation, Structural Characterization, and Cryomagnetic Investigation of New Single-Molecule Magnets
In this work we describe the preparation, spectroscopic, thermal and structural characterization, and cryomagnetic investigation of four new polymorphic derivatives of the [M2(H2mpba)3]2– mesocate ...
Building-up host-guest helicate motifs and chains: a magneto-structural study of new field-induced cobalt-based single-ion magnets.
In this work, we present the synthetic pathway, a refined structural description, complete solid-state characterization and the magnetic properties of four new cobalt(II) compounds of formulas [Co(H2O)6][Co2(H2mpba)3]·2H2O·0.5dmso (1), [Co(H2O)6][Co2(H2mpba)3]·3H2O·0.5dpss (2), [Co2(H2mpba)2(H2O)4]n·4nH2O (3), and [Co2(H2mpba)2(CH3OH)2(H2O)2]n·0.5nH2O·2ndpss (4) [dpss = 2,2′-dipyridyldisulfide and H4mpba = 1,3-phenylenebis(oxamic) acid], where 2 and 4 were obtained from [Co(dpss)Cl2] (Pre-I) as the source of cobalt(II). All four compounds are air-stable and were prepared under ambient conditions. 1 and 2 were obtained from a slow diffusion method [cobalt(II) : H2mpba2− molar ratio used 1 : …
Study of the complex formation between the [Cu(bpca)]+ secondary building unit and the aromatic N donors 2,3,5,6-tetra(2-pyridyl)pyrazine (tppz) and 1,3-bis(4-pyridyl)propane (bpp)
Two new complexes of the formula [{Cu(bpca)}2(μ-tppz)](NO3)2·5H2O (1) and [Cu(bpca)(H2O)(ClO4)(μ-bpp)Cu(bpca)(H2O)2]ClO4·H2O (2) [tppz = 2,3,5,6-tetra(2-pyridyl)pyrazine and bpp = 1,3-bis(4-pyridyl)propane] have been prepared by the reaction of the [Cu(bpca)]+ [Hbpca = bis(2-pyridylcarbonyl)imide] building block and the tppz and bpp N donors. An unusual coordination mode of the tppz ligand was observed in 1, which functions as a bis(bidentate) ligand to two copper(II) atoms each coordinated to a nitrogen atom of the pyrazine moiety and a pyridyl nitrogen atom. This compound presents a layered structure of alternating anionic (ca. 1.6 A) and cationic (ca. 10 A) slices, providing the opportun…
Magneto-structural versatility of copper(II)-3-phenylpropionate coordination polymers with N-donor coligands.
A novel series of copper(II) coordination polymers [Cu2(O2CC8H9)4(pyz)]n (1), [Cu2(O2CC8H9)4(dps)]n (2), {[Cu(O2CC8H9)2(dps)(H2O)]·H2O}n (3), {[NaCu(O2CC8H9)2(bpm)(NO3)]·H2O}n (4), and [Cu4(O2CC8H9)6(OH)2(bpp)2]n (5) [O2CC8H9− = 3-phenylpropionate anion, pyz = pyrazine, dps = di(4-pyridyl)sulfide, bpm = 2,2′-bipyrimidine, and bpp = 1,3-bis(4-pyridyl)propane] have been synthesized and magneto-structurally investigated. Compounds 1 and 2 belong to a large group of copper(II) carboxylates where bis-monodentate pyz (1) and dps (2) ligands connect the paddle-wheel [CuII2(μ-O2CC8H9)4] units leading to alternating copper(II) chains. The structure of 3 consists of uniform chains of trans-[CuII(O2CC…
CCDC 1898457: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 1898455: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 1883575: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Cintia A. Simosono, Iara M. Landre Rosa, Rafaela M. R. da Silva, Antônio C. Doriguetto, Walace D. do Pim, Tatiana R. Gomes Simões, Ana Karoline S. M. Valdo, Felipe T. Martins, Charlie V. Sarmiento, Wallace C. Nunes, Guilherme P. Guedes, Emerson F. Pedroso, Cynthia L. M. Pereira, Humberto O. Stumpf, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2021|Dalton Trans.|50|10707|doi:10.1039/D1DT01693H
CCDC 1559171: Experimental Crystal Structure Determination
Related Article: Eloisa O. Ribeiro, Nathália R. de Campos, Antônio C. Doriguetto, Wdeson P. Barros, Marcos A. Ribeiro, Elgte E. B. De Paula, Humberto O. Stumpf, Francesc Lloret, Miguel Julve, Maria V. Marinho|2017|CrystEngComm|19|5460|doi:10.1039/C7CE01230F
CCDC 1883574: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Cintia A. Simosono, Iara M. Landre Rosa, Rafaela M. R. da Silva, Antônio C. Doriguetto, Walace D. do Pim, Tatiana R. Gomes Simões, Ana Karoline S. M. Valdo, Felipe T. Martins, Charlie V. Sarmiento, Wallace C. Nunes, Guilherme P. Guedes, Emerson F. Pedroso, Cynthia L. M. Pereira, Humberto O. Stumpf, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2021|Dalton Trans.|50|10707|doi:10.1039/D1DT01693H
CCDC 1883576: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Cintia A. Simosono, Iara M. Landre Rosa, Rafaela M. R. da Silva, Antônio C. Doriguetto, Walace D. do Pim, Tatiana R. Gomes Simões, Ana Karoline S. M. Valdo, Felipe T. Martins, Charlie V. Sarmiento, Wallace C. Nunes, Guilherme P. Guedes, Emerson F. Pedroso, Cynthia L. M. Pereira, Humberto O. Stumpf, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2021|Dalton Trans.|50|10707|doi:10.1039/D1DT01693H
CCDC 1898454: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 1409933: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 1993352: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Cintia A. Simosono, Iara M. Landre Rosa, Rafaela M. R. da Silva, Antônio C. Doriguetto, Walace D. do Pim, Tatiana R. Gomes Simões, Ana Karoline S. M. Valdo, Felipe T. Martins, Charlie V. Sarmiento, Wallace C. Nunes, Guilherme P. Guedes, Emerson F. Pedroso, Cynthia L. M. Pereira, Humberto O. Stumpf, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2021|Dalton Trans.|50|10707|doi:10.1039/D1DT01693H
CCDC 1409935: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 1409934: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 1559172: Experimental Crystal Structure Determination
Related Article: Eloisa O. Ribeiro, Nathália R. de Campos, Antônio C. Doriguetto, Wdeson P. Barros, Marcos A. Ribeiro, Elgte E. B. De Paula, Humberto O. Stumpf, Francesc Lloret, Miguel Julve, Maria V. Marinho|2017|CrystEngComm|19|5460|doi:10.1039/C7CE01230F
CCDC 1409932: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 1898456: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 1883577: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Cintia A. Simosono, Iara M. Landre Rosa, Rafaela M. R. da Silva, Antônio C. Doriguetto, Walace D. do Pim, Tatiana R. Gomes Simões, Ana Karoline S. M. Valdo, Felipe T. Martins, Charlie V. Sarmiento, Wallace C. Nunes, Guilherme P. Guedes, Emerson F. Pedroso, Cynthia L. M. Pereira, Humberto O. Stumpf, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2021|Dalton Trans.|50|10707|doi:10.1039/D1DT01693H
CCDC 1409936: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A