0000000000681112
AUTHOR
Iara M. L. Rosa
Polymorphic Derivatives of NiII and CoII Mesocates with 3D Networks and “Brick and Mortar” Structures: Preparation, Structural Characterization, and Cryomagnetic Investigation of New Single-Molecule Magnets
In this work we describe the preparation, spectroscopic, thermal and structural characterization, and cryomagnetic investigation of four new polymorphic derivatives of the [M2(H2mpba)3]2– mesocate ...
Building-up host-guest helicate motifs and chains: a magneto-structural study of new field-induced cobalt-based single-ion magnets.
In this work, we present the synthetic pathway, a refined structural description, complete solid-state characterization and the magnetic properties of four new cobalt(II) compounds of formulas [Co(H2O)6][Co2(H2mpba)3]·2H2O·0.5dmso (1), [Co(H2O)6][Co2(H2mpba)3]·3H2O·0.5dpss (2), [Co2(H2mpba)2(H2O)4]n·4nH2O (3), and [Co2(H2mpba)2(CH3OH)2(H2O)2]n·0.5nH2O·2ndpss (4) [dpss = 2,2′-dipyridyldisulfide and H4mpba = 1,3-phenylenebis(oxamic) acid], where 2 and 4 were obtained from [Co(dpss)Cl2] (Pre-I) as the source of cobalt(II). All four compounds are air-stable and were prepared under ambient conditions. 1 and 2 were obtained from a slow diffusion method [cobalt(II) : H2mpba2− molar ratio used 1 : …
CCDC 1898457: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 1898455: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 1898454: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 1898456: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638