0000000000681859

AUTHOR

Antoine Gomila

showing 4 related works from this author

Aza and cyanobridged tripodal dinuclear copper(II) complexes: Electrochemical studies and structural evidence for an original azacyanocarbanion

2014

International audience; The reactivity of the mononuclear [Cu(TMPA)(L)] n+ complex (TMPA: tris(2-methylpyridine) amine, L: CH3CN, H2O) towards two different bridging species (tetracyanoethylene, 4,40-bipyridine) was investigated. The dinuclear complex [(mu-4,40-bipy)Cu-II(TMPA)(2)](CF3SO3)(4) (1) was synthesised and analysed by Xray diffraction (XRD). Magnetic studies revealed that this derivative displays very weak antiferromagnetic interactions between the two metal centres (2J = -0.69 cm(-1)). Solution studies (EPR spectroscopy and voltammetry) evidenced the lability of the bridged neutral bipyridine ligand in acetonitrile. The reaction of TCNE (TCNE: tetracyanoethylene) with the copper(…

010405 organic chemistryChemistryStereochemistrychemistry.chemical_elementCrystal structureTetracyanoethylene010402 general chemistryElectrochemistry01 natural sciencesCopper0104 chemical scienceslaw.inventionInorganic Chemistrychemistry.chemical_compoundCrystallographyBipyridinelaw[CHIM.ANAL]Chemical Sciences/Analytical chemistryMaterials ChemistryAmine gas treating[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical ChemistryElectron paramagnetic resonanceAcetonitrile
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CCDC 959981: Experimental Crystal Structure Determination

2014

Related Article: Antoine Gomila, Benedicte Douziech, Nathalie Cosquer, Nicolas Le Poul, Francois Michaud, Carlos J. Gomez-Garcia, Yves Le Mest, Francoise Conan|2014|Inorg.Chim.Acta|411|67|doi:10.1016/j.ica.2013.11.024

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu2-cyano)-bis(NNN-tris((pyridin-2-yl)methyl)amine)-di-copper tris(hexafluorophosphate) diethyl ether solvateExperimental 3D Coordinates
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CCDC 959979: Experimental Crystal Structure Determination

2014

Related Article: Antoine Gomila, Benedicte Douziech, Nathalie Cosquer, Nicolas Le Poul, Francois Michaud, Carlos J. Gomez-Garcia, Yves Le Mest, Francoise Conan|2014|Inorg.Chim.Acta|411|67|doi:10.1016/j.ica.2013.11.024

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(mu2-44'bipyridine)-bis(NNN-tris(pyridin-2-ylmethyl)amine)-di-copper(ii) tetrakis(trifluoromethanesulfonate) hemihydrate
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CCDC 959980: Experimental Crystal Structure Determination

2014

Related Article: Antoine Gomila, Benedicte Douziech, Nathalie Cosquer, Nicolas Le Poul, Francois Michaud, Carlos J. Gomez-Garcia, Yves Le Mest, Francoise Conan|2014|Inorg.Chim.Acta|411|67|doi:10.1016/j.ica.2013.11.024

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu2-cyano)-bis(NNN-tris(pyridin-2-ylmethyl)amine)-di-copper(ii) N-(tetracyanocyclopentadienyl)-3-aza-112-tricyanoprop-1-enide hexafluorophosphate acetonitrile solvateExperimental 3D Coordinates
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