0000000000698776

AUTHOR

Eli Zysman-colman

Green phosphorescence and electroluminescence of sulfur pentafluoride-functionalized cationic iridium(III) complexes

EZ-C acknowledges the University of St Andrews for financial support. We report four cationic iridium(III) complexes [Ir(C^N)2(dtBubpy)](PF6) that have sulfurpentafluoride-modified 1-phenylpyrazole and 2-phenylpyridine cyclometalating (C^N) ligands (dtBubpy = 4,4'-di-tert-butyl-2,2'-bipyridyl). Three of the complexes were characterized by single-crystal X-ray structure analysis. In cyclic voltammetry, the complexes undergo reversible oxidation of iridium(III) and irreversible reduction of the SF5 group. They emit bright green phosphorescence in acetonitrile solution and in thin films at room temperature, with emission maxima between 482–519 nm and photoluminescence quantum yields of up to 7…

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Tuning the Emission of Cationic Iridium (III) Complexes Towards the Red Through Methoxy Substitution of the Cyclometalating Ligand

The synthesis, characterization and evaluation in solid-state devices of a series of 8 cationic iridium complexes bearing different numbers of methoxy groups on the cyclometallating ligands are reported. The optoelectronic characterization showed a dramatic red shift in the absorption and the emission and a reduction of the electrochemical gap of the complexes when a methoxy group was introduced para to the Ir-C bond. The addition of a second or third methoxy group did not lead to a significant further red shift in these spectra. Emission maxima over the series ranged from 595 to 730 nm. All complexes possessing a motif with a methoxy group at the 3-position of the cyclometalating ligands s…

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Wide-Bite-Angle Diphosphine Ligands in Thermally Activated Delayed Fluorescent Copper(I) Complexes: Impact on the Performance of Electroluminescence Applications.

We report a series of seven cationic heteroleptic copper(I) complexes of the form [Cu(P^P)(dmphen)]BF4, where dmphen is 2,9-dimethyl-1,10-phenanthroline and P^P is a diphosphine chelate, in which the effect of the bite angle of the diphosphine ligand on the photophysical properties of the complexes was studied. Several of the complexes exhibit moderately high photoluminescence quantum yields in the solid state, with ΦPL of up to 35%, and in solution, with ΦPL of up to 98%. We were able to correlate the powder photoluminescence quantum yields with the % Vbur of the P^P ligand. The most emissive complexes were used to fabricate both organic light-emitting diodes and light-emitting electrochem…

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Impact of the use of sterically congested Ir(III) complexes on the performance of light-emitting electrochemical cells

International audience; The synthesis, structural and optoelectronic characterization of a family of sterically congested cyclometalated cationic Ir(iii) complexes of the form [Ir(C^N)2(dtBubpy)]PF6 (with dtBubpy = 4,4′-di-tert-butyl-2,2′-bipyridine and C^N = a cyclometalating ligand decorated at the 4-position of the pyridine ring and/or the 3-position of the phenyl ring with a range of sterically bulky substituents) are reported. This family of complexes is compared to the unsubstituted analogue complex R1 bearing 2-phenylpyridinato as cyclometalating ligand. The impact of sterically bulky substituents on the C^N ligands on both the solid state photophysics and light-emitting electrochemi…

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Light-emitting electrochemical cells and solution-processed organic light-emitting diodes using small molecule organic thermally activated delayed fluorescence emitters

EZ-C thanks the University of St Andrews for support. The authors are grateful to the EPSRC for financial support (grants EP/J01771X and EP/J00916). IDWS is a Royal Society Wolfson Research Merit Award Holder. Two novel charged organic thermally activated delayed fluorescence (TADF) emitters, 1 and 2, have been synthesized. Their TADF behavior is well-supported by the multiexponential decay of their emission (nanosecond and microsecond components) and the oxygen dependence of the photoluminescence quantum yields. Spin-coated electroluminescent devices have been fabricated to make light-emitting electrochemical cells (LEECs) and organic light-emitting diodes (OLEDs). The first example of a n…

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Ionic multiresonant thermally activated delayed fluorescence emitters for light emitting electrochemical cells

Funding: M. K. would like to thank 2214-A International Research Fellowship Programme for Ph.D. students (1059B141900585). This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska Curie grant agreement No 838885 (NarrowbandSSL). S.M.S. acknowledges support from the Marie Skłodowska-Curie Individual Fellowship (grant agreement No 838885 NarrowbandSSL). A. K. G. is grateful to the Royal Society for Newton International Fellowship NF171163. L.M acknowledges that the project who gave rise to these results received support from the European Research Council (ERC) under the European Union’s Horizon 2020 research and inno…

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Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(iii) complexes bearing bisphosphine ligands

EZ-C acknowledges the University of St Andrews for financial support. We thank Johnson Matthey and Umicore AG for the gift of materials and Cihang Yu for the preparation of isopropxantphos. We thank Dr. Nail Shaveleev for the synthesis of NMS25. IDWS and AKB acknowledge support from EPSRC (EP/J01771X). This work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO) MAT2014-55200. Herein we present a structure-property relationship study of thirteen cationic iridium (III) complexes of the form of [Ir(C^N)2(P^P)]PF6 in both solution and the solid state through systematic evaluation of six bisphosphine (P^P) ligands (xantphos, dpephos, dppe, Dppe, nixantphos and is…

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Fluorine-free blue-green emitters for light-emitting electrochemical cells

Date of Acceptance: 29/05/2014 There is presently a lack of efficient and stable blue emitters for light-emitting electrochemical cells (LEECs), which limits the development of white light emitting systems for lighting. Cyclometalated iridium complexes as blue emitters tend to show low photoluminescence efficiency due to significant ligand-centred character of the radiative transition. The most common strategy to blue-shift the emission is to use fluorine substituents on the cyclometalating ligand, such as 2,4-difluorophenylpyridine, dFppy, which has been shown to decrease the stability of the emitter in operating devices. Herein we report a series of four new charged cyclometalated iridium…

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Deep-blue thermally activated delayed fluorescence (TADF) emitters for light-emitting electrochemical cells (LEECs)

The authors acknowledge the University of St Andrews for financial support. The authors also acknowledge financial support from the European Union H2020 project INFORM (grant 675867), the Spanish Ministry of Economy and Competitiveness (MINECO) via the Unidad de Excelencia María de Maeztu MDM-2015-0538, MAT2014-55200 and the Generalitat Valenciana (Prometeo/2016/135). MLP acknowledges support from a Grisolia grant (GRISOLIA/2015/A/146). Two deep blue thermally activated delayed fluorescence (TADF) emitters ( imCzDPS and imDPADPS ) that contain charged imidazolium groups tethered to the central luminophore were designed and synthesized as small molecule organic emitters for light-emitting e…

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Efficient light-emitting electrochemical cells using small molecular weight, ionic, host-guest systems

This work has been supported by the Spanish Ministry of Economy and Competitiveness (MAT2014-55200). Light-emitting electrochemical cells (LECs) based on fluorescent host-guest small molecules system are reported. The LECs show electroluminescence coming solely from the guest, with an external quantum efficiency (EQE) of 2.0%, which is very close to the theoretical maximum EQE (2.2%) for this particular system. This work demonstrates the possibility to obtain high efficiency devices employing low-cost materials, making host-guest systems a real alternative to more traditional semiconducting polymer or transition metal compounds. Postprint Peer reviewed

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CCDC 1490702: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

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CCDC 1423252: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

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Ionic Multi-Resonant Thermally Activated Delayed Fluorescence Emitters for Light Emitting Electrochemical Cells (dataset)

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CCDC 1546695: Experimental Crystal Structure Determination

Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F

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Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(III) complexes bearing bisphosphine ligands (dataset)

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CCDC 1490703: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

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CCDC 1423251: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

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CCDC 2061123: Experimental Crystal Structure Determination

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

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CCDC 1490707: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

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CCDC 1546696: Experimental Crystal Structure Determination

Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F

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CCDC 1423253: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

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CCDC 2061124: Experimental Crystal Structure Determination

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

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CCDC 2061121: Experimental Crystal Structure Determination

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

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CCDC 1053872: Experimental Crystal Structure Determination

Related Article: Nail M. Shavaleev, Guohua Xie, Shinto Varghese, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortí, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2015|Inorg.Chem.|54|5907|doi:10.1021/acs.inorgchem.5b00717

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CCDC 1053870: Experimental Crystal Structure Determination

Related Article: Nail M. Shavaleev, Guohua Xie, Shinto Varghese, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortí, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2015|Inorg.Chem.|54|5907|doi:10.1021/acs.inorgchem.5b00717

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CCDC 2061118: Experimental Crystal Structure Determination

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

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Blue-Emitting Cationic Iridium(III) Complexes Featuring Pyridylpyrimidine Cyclometalating Ligands and their Use in Sky-Blue and Blue-Green Light-Emitting Electrochemical Cells (LEECs) and Organic Light-Emitting Diodes (OLEDs) (dataset)

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CCDC 1423259: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

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CCDC 2061119: Experimental Crystal Structure Determination

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

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CCDC 1490708: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

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CCDC 1490705: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

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CCDC 1546698: Experimental Crystal Structure Determination

Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F

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CCDC 1490429: Experimental Crystal Structure Determination

Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortı́, Ifor D. W. Samuel, Henk J. Bolink, and Eli Zysman-Colman|2016|Inorg.Chem.|55|10361|doi:10.1021/acs.inorgchem.6b01602

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CCDC 1423255: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

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Data Underpinning - Tuning the emission of cationic iridium (III) complexes towards the red through methoxy substitution of the cyclometalating ligand

EZ-C acknowledges CFI (Canadian Foundation for Innovation), NSERC (the Natural Sciences and Engineering Research Council of Canada), FQRNT (Le Fonds québécois de la recherche sur la nature et les technologies) and the University of St Andrews for financial support. C. R-C. would like to thank the MINECO for the financial support of this research in the framework of project CTQ2010-17481, the Junta de Andalucía (CICyE) for special financial support (P08-FQM-4011 and P10-FQM-6703) and the MECD (Spanish Ministry of Education, Culture, and Sport) for an FPU grant. This work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO) (MAT2014-55200), the Generalitat Valenc…

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CCDC 1538393: Experimental Crystal Structure Determination

Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Eli Zysman-Colman|2017|RSC Advances|7|31833|doi:10.1039/C7RA06347D

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CCDC 1538394: Experimental Crystal Structure Determination

Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Eli Zysman-Colman|2017|RSC Advances|7|31833|doi:10.1039/C7RA06347D

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Impact of the Use of Sterically Congested Cyclometalated Ligands on the Optoelectronic Properties and Device Performances In Light-Emitting Electrochemical Cells of Cationic Iridium(III) Complexes (dataset)

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CCDC 1423254: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

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CCDC 2061120: Experimental Crystal Structure Determination

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

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CCDC 1490428: Experimental Crystal Structure Determination

Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortı́, Ifor D. W. Samuel, Henk J. Bolink, and Eli Zysman-Colman|2016|Inorg.Chem.|55|10361|doi:10.1021/acs.inorgchem.6b01602

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Wide Bite Angle Disphosphine Ligands in Thermally Activated Delayed Fluorescent Copper(I) Complexes: Impact on the Performance of Electroluminescence Applications (dataset)

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Data underpinning - Chiral Iridium(III) Complexes in Light-Emitting Electrochemical Cells: Exploring The Impact of Stereochemistry on The Photophysical Properties and Device Performances

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CCDC 1546697: Experimental Crystal Structure Determination

Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F

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CCDC 2061122: Experimental Crystal Structure Determination

Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804

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CCDC 1423258: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

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CCDC 1490430: Experimental Crystal Structure Determination

Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortı́, Ifor D. W. Samuel, Henk J. Bolink, and Eli Zysman-Colman|2016|Inorg.Chem.|55|10361|doi:10.1021/acs.inorgchem.6b01602

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CCDC 1423257: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

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Simple Design to Achieve Red-to-Near-infrared Emissive Cationic Ir(III) Emitters and their use in Light Emitting Electrochemical Cells (dataset)

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CCDC 1490706: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

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CCDC 1490704: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050

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CCDC 1053871: Experimental Crystal Structure Determination

Related Article: Nail M. Shavaleev, Guohua Xie, Shinto Varghese, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortí, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2015|Inorg.Chem.|54|5907|doi:10.1021/acs.inorgchem.5b00717

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CCDC 1423256: Experimental Crystal Structure Determination

Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C

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Data underpinning - Synthesis, Properties and Light-Emitting Electrochemical Cell (LEEC) Device Fabrication of Cationic Ir(III) Complexes Bearing Electron-Withdrawing Groups on the Cyclometallating Ligands

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CCDC 1490431: Experimental Crystal Structure Determination

Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortı́, Ifor D. W. Samuel, Henk J. Bolink, and Eli Zysman-Colman|2016|Inorg.Chem.|55|10361|doi:10.1021/acs.inorgchem.6b01602

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Deep-Blue Thermally Activated Delayed Fluorescence (TADF) Emitters for Light-Emitting Electrochemical Cells (LEECs) (dataset)

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