Author: Marcos D. Codesal

0000000000700798

AUTHOR

Marcos D. Codesal

showing 2 related works from this author

Heptagon-Containing Nanographene Embedded into [10]Cycloparaphenylene

2023

We report the synthesis and characterization of a novel type of nanohoop, consisting of a cycloparaphenylene derivative incorporating a curved heptagon-containing π-extended polycyclic aromatic hydrocarbon (PAH) unit. We demonstrate that this new macrocycle behaves as a supramolecular receptor of curved π-systems such as fullerenes C60 and C70, with remarkably large binding constants (ca. 107 M−1), as estimated by fluorescence measurements. Nanosecond and femtosecond spectroscopic analysis show that these host-guest complexes are capable of quasi-instantaneous charge separation upon photoexcitation, due to the ultrafast charge transfer from the macrocycle to the complexed fullerene. These r…

NanographenesTransient Absorption SpectroscopySettore FIS/01 - Fisica SperimentaleGeneral MedicineGeneral ChemistryCycloparaphenylenesHost-Guest SystemsMacrocyclesCatalysis

researchProduct

CCDC 2237075: Experimental Crystal Structure Determination

2023

Related Article: Juan P. Mora-Fuentes, Marcos D. Codesal, Marco Reale, Carlos M. Cruz, Vicente G. Jiménez, Alice Sciortino, Marco Cannas, Fabrizio Messina, Victor Blanco, Araceli G. Campaña|2023|Angew.Chem.,Int.Ed.|62||doi:10.1002/anie.202301356

Space GroupCrystallographyCrystal Systemcyclo-145:7414:1121:2431:3441:4451:5461:6471-septiphenyl-(811-di-t-butyl-19H-benzo[5'6']tetraceno[1'12'11'10':56789]tetrapheno[1011121-nopqab]pleiaden-19-one) unknown solvateCrystal StructureCell ParametersExperimental 3D Coordinates

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PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
  - PE2_1Theory of fundamental interactions
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  - PE2_10Atomic, molecular physics
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- PE1Mathematics
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LSLife Sciences
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SHSocial Sciences and Humanities
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