Exploration of the Solid-State Sorption Properties of Shape-Persistent Macrocyclic Nanocarbons as Bulk Materials and Small Aggregates.
Porous molecular materials combine benefits such as convenient processability and the possibility for atom-precise structural fine-tuning which makes them remarkable candidates for specialty applications in the areas of gas separation, catalysis, and sensing. In order to realize the full potential of these materials and guide future molecular design, knowledge of the transition from molecular properties into materials behavior is essential. In this work, the class of compounds termed cycloparaphenylenes (CPPs)-shape-persistent macrocycles with built-in cavities and radially oriented π-systems-was selected as a conceptually simple class of intrinsically porous nanocarbons to serve as a platf…
CCDC 1961176: Experimental Crystal Structure Determination
Related Article: Tobias A. Schaub, Ephraim A. Prantl, Julia Kohn, Markus Bursch, Checkers R. Marshall, Erik J. Leonhardt, Terri C. Lovell, Lev N. Zakharov, Carl K. Brozek, Siegfried R. Waldvogel, Stefan Grimme, Ramesh Jasti|2020|J.Am.Chem.Soc.|142|8763|doi:10.1021/jacs.0c01117
CCDC 1961177: Experimental Crystal Structure Determination
Related Article: Tobias A. Schaub, Ephraim A. Prantl, Julia Kohn, Markus Bursch, Checkers R. Marshall, Erik J. Leonhardt, Terri C. Lovell, Lev N. Zakharov, Carl K. Brozek, Siegfried R. Waldvogel, Stefan Grimme, Ramesh Jasti|2020|J.Am.Chem.Soc.|142|8763|doi:10.1021/jacs.0c01117
CCDC 1961179: Experimental Crystal Structure Determination
Related Article: Tobias A. Schaub, Ephraim A. Prantl, Julia Kohn, Markus Bursch, Checkers R. Marshall, Erik J. Leonhardt, Terri C. Lovell, Lev N. Zakharov, Carl K. Brozek, Siegfried R. Waldvogel, Stefan Grimme, Ramesh Jasti|2020|J.Am.Chem.Soc.|142|8763|doi:10.1021/jacs.0c01117