0000000000710055
AUTHOR
E. Kestilä
Effect of the crystallization on the phase transitions IV ⇐ III and IV ⇐ II of ammonium nitrate
Abstract The solid state phase transition path of ammonium nitrate is influenced by the manner of crystallization. Slow crystallization from water gives ideal crystals, which behaved differently from crystals prepared by rapid crystallization from the melt.
Differential scanning calorimetric and Raman studies of phase transition V ⇌ IV of ammonium nitrate
Abstract Differential scanning calorimetry, alone and in conjunction with Raman spectrophotometry for simultaneous calorimetric and spectral measurements, was used to study the solid state phase transitions of ammonium nitrate between − 50 and 100 °C. On heating, two transition paths were observed between − 40 and 0 °C: one showing two separate peaks in DSC and the other showing a single peak. The latter path became dominant when samples were thermally cycled. The double transition was followed by transition IV →II at 51 °C and the single transition by transitions IV → III → II at about 50 and 87 °C. Raman spectra showed that there were two phases present between the two DSC peaks at low te…