Three‐in‐One Crystal: The Coordination Diversity of Zinc Polypyridine Complexes
The synthesis, structural and photophysical properties of two novel zinc(II) complexes bearing the tridentate ddpd (N,N' dimethyl N,N' dipyridin 2 ylpyridine 2,6 diamine) ligand are presented. Structural investigations have been carried out by single crystal X-ray diffractometry, NMR spectroscopy and Density Functional Theory calculations, revealing a diverse coordination behavior depending on the counter ion. Spectroscopic (UV-VIS and emission spectroscopy) and theoretical techniques (density functional theory and time dependent DFT calculations) have been employed to explore the photophysical properties of the complexes.
CCDC 1555799: Experimental Crystal Structure Determination
Related Article: Sven Otto, Johannes Moll, Christoph Förster, Daniel Geißler, Cui Wang, Ute Resch-Genger, Katja Heinze|2017|Eur.J.Inorg.Chem.||5033|doi:10.1002/ejic.201700948
CCDC 1555798: Experimental Crystal Structure Determination
Related Article: Sven Otto, Johannes Moll, Christoph Förster, Daniel Geißler, Cui Wang, Ute Resch-Genger, Katja Heinze|2017|Eur.J.Inorg.Chem.||5033|doi:10.1002/ejic.201700948