0000000000714055
AUTHOR
J.m. Dominguez-vera
One-dimensional iron(III) and two-dimensional iron(III)nickel(II) cyanide-bridged ferromagnetic arrays from hexacyanoferrate(III) and [Ni(cyclam)]2+ building blocks: Synthesis, crystal structure and magnetic properties
Abstract The X-ray structures and magnetic properties of a iron(III) linear chain and a honeycomb-like layered iron(III)-nickel(II) cyanide-bridged compound are reported. The former contains alternating iron sites and unexpected ferromagnetic behaviour, justified on the basis of the axial distortion from regular octahedral geometry of one of the iron ions. The latter is metamagnetic with ferromagnetic intralayers and antiferromagnetic interlayers interactions with a Neel temperature, TN= 7.7 K. The field-induced transition from an antiferro- to a ferromagnetic state takes place at Hc= 5000 G. The antiferromagnetic ordered phase exhibits spin-canting and long range ferromagnetic ordering at …
CCDC 119191: Experimental Crystal Structure Determination
Related Article: E.Colacio, J.M.Dominguez-Vera, M.Ghazi, R.Kivekas, F.Lloret, J.M.Moreno, H.Stoeckli-Evans|1999|Chem.Commun.||987|doi:10.1039/a902041a
CCDC 119192: Experimental Crystal Structure Determination
Related Article: E.Colacio, J.M.Dominguez-Vera, M.Ghazi, R.Kivekas, F.Lloret, J.M.Moreno, H.Stoeckli-Evans|1999|Chem.Commun.||987|doi:10.1039/a902041a
CCDC 204969: Experimental Crystal Structure Determination
Related Article: E.Colacio, J.M.Dominguez-Vera, F.Lloret, A.Rodriguez, H.Stoeckli-Evans|2003|Inorg.Chem.|42|6962|doi:10.1021/ic034307l