0000000000718141

AUTHOR

Jacky C.-h. Yim

showing 3 related works from this author

Synthesis and properties of an Au6 cluster supported by a mixed N-heterocyclic carbene–thiolate ligand

2020

The preparation of a novel Au6 cluster bearing a bidentate mixed carbene–thiolate ligand is presented. The length of linker between the central benzimidazole and thiolate has a strong effect on the formation of cluster products, with a C2 chain giving an Au6 cluster, while a C3 chain results in no evidence of cluster formation. Density functional theory analysis predicts a non-metallic cluster with a large HOMO–LUMO (3.2–3.6 eV) and optical gap.

BenzimidazoleDenticity010405 organic chemistryLigandMetals and AlloysGeneral Chemistry010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundCrystallographychemistryChain (algebraic topology)Materials ChemistryCeramics and CompositesCluster (physics)Density functional theoryCarbeneLinkerChemical Communications
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CCDC 1985367: Experimental Crystal Structure Determination

2020

Related Article: Kirsi Salorinne, Renee W. Y. Man, Paul A. Lummis, Maryam Sabooni Asre Hazer, Sami Malola, Jacky C.-H. Yim, Alex J. Veinot, Wenxia Zhou, Hannu Häkkinen, Masakazu Nambo, Cathleen M. Crudden|2020|Chem.Commun.|56|6102|doi:10.1039/D0CC01482F

Space GroupCrystallographyCrystal SystemCrystal Structure{1-[2-(acetylsulfanyl)ethyl]-3-isopropylbenzimidazol-2-ylidene}-bromo-gold(i)Cell ParametersExperimental 3D Coordinates
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CCDC 1985364: Experimental Crystal Structure Determination

2020

Related Article: Kirsi Salorinne, Renee W. Y. Man, Paul A. Lummis, Maryam Sabooni Asre Hazer, Sami Malola, Jacky C.-H. Yim, Alex J. Veinot, Wenxia Zhou, Hannu Häkkinen, Masakazu Nambo, Cathleen M. Crudden|2020|Chem.Commun.|56|6102|doi:10.1039/D0CC01482F

Space GroupCrystallographytetrakis(mu-1-isopropyl-3-(2-thiolatoethyl)benzimidazol-2-ylidene)-hexa-gold bis(hexafluorophosphate) ethanol solvate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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