showing 5 related works from this author
X-ray snapshot observation of palladium-mediated aromatic bromination in a porous complex
2014
Pd-mediated aromatic bromination is intriguing to synthetic and organometallic chemists due to both its synthetic utility and, more importantly, a proposed mechanism involving an uncommon Pd(IV)/Pd(II) catalytic cycle. Here, we report an X-ray snapshot observation of a Pd reaction center during a Pd-mediated aromatic bromination in a single crystal of a porous coordination network crystalline scaffold. Upon treatment of a single crystal with N-bromosuccinimide, sequential X-ray snapshots revealed that the aryl-Pd(II)-L species embedded in the network pores was converted to the brominated aryl product through a transient aryl-Pd(II)-Br species, which is normally unobservable because of its r…
CCDC 1003159: Experimental Crystal Structure Determination
2014
Related Article: Koki Ikemoto , Yasuhide Inokuma , Kari Rissanen , and Makoto Fujita|2014|J.Am.Chem.Soc.|136|6892|doi:10.1021/ja502996h
CCDC 967380: Experimental Crystal Structure Determination
2014
Related Article: Koki Ikemoto , Yasuhide Inokuma , Kari Rissanen , and Makoto Fujita|2014|J.Am.Chem.Soc.|136|6892|doi:10.1021/ja502996h
CCDC 967381: Experimental Crystal Structure Determination
2014
Related Article: Koki Ikemoto , Yasuhide Inokuma , Kari Rissanen , and Makoto Fujita|2014|J.Am.Chem.Soc.|136|6892|doi:10.1021/ja502996h
CCDC 967379: Experimental Crystal Structure Determination
2014
Related Article: Koki Ikemoto , Yasuhide Inokuma , Kari Rissanen , and Makoto Fujita|2014|J.Am.Chem.Soc.|136|6892|doi:10.1021/ja502996h