showing 3 related works from this author
Azido bridged binuclear copper(ii) Schiff base compound: synthesis, structure and electrical properties
2019
An azido bridged dinuclear complex [Cu(L−)(μ1,1N3)]2 (1) was synthesized by a 1 : 1 condensation of N-cyclohexyl-1,3-propanediamine and 5-bromosalicylaldehyde (HL). The complex was subsequently characterized based on elemental analyses, IR, single-crystal X-ray diffraction, a Hirshfeld study, FESEM, ESI-MS, powder XRD and also DFT studies successfully. The X-ray crystal structure of complex 1 revealed that the Cu(II) ion exhibited a definite five-coordinate square pyramidal coordination arrangement with a centro-symmetric μ 1,1-azido bridging in the end-on mode and formed a dimeric structure. The optical direct band gap of complex 1 was estimated to be 2.84 eV. The current–voltage character…
Synthesis and characterization of a novel dicyanamide-bridged Co(II) 1-D coordination polymer with a N 4 -donor Schiff base ligand
2017
The synthesis, structure and magnetic properties of a novel Co(II) 1D coordination polymer, [Co(L)(µ1,5-dca)(ClO4)2·MeOH]n (1) are described. Compound 1 contains two independent cationic Co(II) chains (CoA and CoB) which are parallel to the c direction and present short π-π and C-H⋯π interactions with two neighbouring chains along the b direction, giving rise to alternating layers of chains A and B in the bc plane. Variable-temperature magnetic susceptibility measurements shows a weak antiferromagnetic coupling among the adjacent cobalt(II) centres mediated through μ1,5-dca− bridge.
CCDC 1478367: Experimental Crystal Structure Determination
2017
Related Article: Saikat Banerjee, Sattwick Halder, Paula Brandão, Carlos J. Gómez García, Samia Benmansour, Amrita Saha|2017|Inorg.Chim.Acta|464|65|doi:10.1016/j.ica.2017.04.056