0000000000729003

AUTHOR

Lourdes Piqueres-vidal

showing 2 related works from this author

Cycloaddition reactions of 1-tert-butyl-4-vinylpyrazole

1989

1-tert-Butyl-4-vinylpyrazole1 a reacts with dimethyl acetylenedicarboxylate (DMAD), methyl propiolate (MP) and N-phenylmaleimide (NPMI) affording the indazole derivatives2,3, and5 as a result of a Diels-Alder ([4 + 2]) cycloaddition. With diethylazodicarboxylate (DEAZD), tetracyanoethylene (TCNE) and 4-phenyl-1,2,4-triazole-3,5-dione (PTAD) the reaction takes place exclusively through the olefinic substituent and the adducts6,7, and9 were isolated. The alkenylpyrazoles1 b–d reacted withDMAD and N-phenylmaleimide to give polymers.

Dimethyl acetylenedicarboxylateTert butylchemistry.chemical_compoundIndazolechemistryMethyl propiolateDiels alderSubstituentOrganic chemistryGeneral ChemistryTetracyanoethyleneMedicinal chemistryCycloadditionMonatshefte f�r Chemie Chemical Monthly
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ChemInform Abstract: Cycloaddition Reactions of 1-tert.-Butyl-4-vinylpyrazole.

1990

1-tert-Butyl-4-vinylpyrazole1 a reacts with dimethyl acetylenedicarboxylate (DMAD), methyl propiolate (MP) and N-phenylmaleimide (NPMI) affording the indazole derivatives2,3, and5 as a result of a Diels-Alder ([4 + 2]) cycloaddition. With diethylazodicarboxylate (DEAZD), tetracyanoethylene (TCNE) and 4-phenyl-1,2,4-triazole-3,5-dione (PTAD) the reaction takes place exclusively through the olefinic substituent and the adducts6,7, and9 were isolated. The alkenylpyrazoles1 b–d reacted withDMAD and N-phenylmaleimide to give polymers.

Dimethyl acetylenedicarboxylateTert butylchemistry.chemical_compoundIndazolechemistryMethyl propiolateSubstituentGeneral MedicineTetracyanoethyleneMedicinal chemistryCycloadditionChemInform
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