0000000000730009

AUTHOR

G. Ouvrard

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Synthesis and characterization of copper intercalated ZrTe3

1997

Abstract Electrochemical copper intercalation in ZrTe3 yields the new metallic ternary phase CuxZrTe3 with a maximum stoichiometry of x = 1.9. The charge is balanced by filling the σ∗ antibonding Te p bands, as monitored by XANES spectroscopy. The reaction is accompanied by an increase in the a lattice dimension of 9%. This observation is explained by theoretical calculations.

Materials scienceMechanical EngineeringIntercalation (chemistry)Inorganic chemistryMetals and Alloyschemistry.chemical_elementAntibonding molecular orbitalTernary phaseElectrochemistryCopperMetalCrystallographychemistryMechanics of MaterialsLattice (order)visual_artMaterials Chemistryvisual_art.visual_art_mediumStoichiometry
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