Author: Lijo George

0000000000735684

AUTHOR

Lijo George

0000-0002-4176-7078

showing 2 related works from this author

Deoxygenative Divergent Synthesis : En Route to Quinic Acid Chirons

2020

The installation of vicinal mesylate and silyl ether groups in a quinic acid derivative generates a system prone for stereoselective borane-catalyzed hydrosilylation through a siloxonium intermediate. The diversification of the reaction conditions allowed the construction of different defunctionalized fragments foreseen as useful synthetic fragments. The selectivity of the hydrosilylation was rationalized on the basis of deuteration experiments and computational studies. peerReviewed

Hydrosilylation010402 general chemistry01 natural sciencesBiochemistrySilyl etherchemistry.chemical_compoundredox reactionsPhysical and Theoretical Chemistryhapetus-pelkistysreaktioorgaaniset yhdisteeteetteritkemiallinen synteesi010405 organic chemistryreaction productsOrganic ChemistryhydrosilylationQuinic acidCombinatorial chemistry0104 chemical sciencesbond cleavageetherschemistryStereoselectivitySelectivityDivergent synthesisDerivative (chemistry)Vicinal

researchProduct

CCDC 2005907: Experimental Crystal Structure Determination

2020

Related Article: Suvi Holmstedt, Lijo George, Alisa Koivuporras, Arto Valkonen, Nuno R. Candeias|2020|Org.Lett.|22|8370|doi:10.1021/acs.orglett.0c02995

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-{[(35-dinitrobenzoyl)oxy]methyl}cyclohexane-12-diyl bis(35-dinitrobenzoate)Experimental 3D Coordinates

researchProduct

PEPhysical Sciences and Engineering
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